Anomalous shear banding revisited with Rheo-NMR and Rheo-USV

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• 作者：Stefan Kuczera ; Christophe Perge ; Marc-Antoine Fardin ; Timothy I. Brox…
• 关键词：Rheo ; NMR ; Rheo ; USV ; Wormlike micelles ; Shear banding ; Slip
• 刊名：Rheologica Acta
• 出版年：2015
• 出版时间：July 2015
• 年：2015
• 卷：54
• 期：7
• 页码：619-636
• 全文大小：2,334 KB
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• 作者单位：Stefan Kuczera (1)
  Christophe Perge (2)
  Marc-Antoine Fardin (2)
  Timothy I. Brox (1)
  Martin A. K. Williams (3)
  S茅bastien Manneville (2)
  Petrik Galvosas (1)
  
  1. Victoria University of Wellington, SCPS, MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand
  2. Laboratoire de Physique, 脡cole Normale Sup茅rieure de Lyon, CNRS UMR 5672 鈥?6 all茅e d鈥橧talie, Universit茅 de Lyon, 69364, Lyon, cedex 07, France
  3. Institute of Fundamental Sciences, Massey University, Palmerston North, New Zealand
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Characterization and Evaluation Materials
  Polymer Sciences
  Mechanical Engineering
  Soft Matter and Complex Fluids
  Food Science
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1435-1528

文摘

A combined two-dimensional Rheo-NMR velocimetry and two-dimensional Rheo-USV approach is used to further elucidate the flow of a wormlike micellar solution in cylindrical Couette geometries. Recent experimental enhancements for both methods enable a more detailed description of the flow dynamics than available in the past. This enabled us to revisit and investigate shear banded flow utilizing improved spatial and temporal resolution, clearly confirming a departure from a simple lever rule for the micellar solution under study. Both experimental techniques observe different shear rates in the high shear rate band accompanied by a varying position of the interface between bands for different applied shear rates. Furthermore, spatially and temporally resolved velocimetry reveals various flow instabilities. Ultrasound measurements show vorticity undulations with wavelengths that scale linearly with the size of the high shear rate band. For high enough shear rates, the occurrence of turbulent bursts is detected in the USV case. However, no direct evidence of these bursts is found in the NMR measurements for equivalent shear rates, which we attribute so far to differences in the design of the shearing geometries.