High-efficiency removal of NO x by a novel integrated chemical absorption and two-stage bioreduction process using magnetically stabilized fluidized bed reactors
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- 作者：Zuoming Zhou ; Tianming Lin ; Guohua Jing ; Bihong Lv ; Yixuan Liu
- 关键词：nitrogen oxides ; flue gas ; immobilized bacteria ; magnetically stabilized fluidized bed
- 刊名：SCIENCE CHINA Chemistry
- 出版年：2015
- 出版时间：October 2015
- 年：2015
- 卷：58
- 期：10
- 页码：1621-1630
- 全文大小：987 KB
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Tianming Lin (1)
Guohua Jing (1)
Bihong Lv (1)
Yixuan Liu (1)
1. Department of Environmental Science & Engineering, Huaqiao University, Xiamen, 361021, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Chinese Library of Science
Chemistry - 出版者：Science China Press, co-published with Springer
- ISSN：1869-1870
文摘
To enhance the bioregeneration of Fe(II)EDTA and to avoid the inhibition of the components in nitrogen oxides (NO x ) scrubbing solution, a novel integrated process of metal chelate absorption and two-stage bioreduction was developed. In this process, magnetically stabilized fluidized beds (MSFB) were used as the bioreactors, and the phase diagram for the MSFB operation was determined. Factors including inlet NO, O2 and SO2 concentrations, magnetic field intensity, gas flow rate and liquid circulation rate, were studied experimentally to investigate their effects on NO removal. In addition, a mathematical model for NO removal in this integrated system was developed. The results revealed that the integrated system could be steadily operated with a high NO removal efficiency and elimination capacity, even under the condition of high NO and O2 shock-loading. The established model showed that NO removal efficiency was related to the spray column property and the active Fe(II)EDTA concentration, while the latter depends on the bioregeneration of the disabled absorbent in the MSFB. Keywords nitrogen oxides flue gas immobilized bacteria magnetically stabilized fluidized bed