Partitioning of the pesticide trifluralin between dissolved organic matter and water using automated SPME-GC/MS

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• 作者：Emilie Caupos (1) (2)
  Arnaud Touffet (1)
  Patrick Mazellier (3)
  Jean-Philippe Croue (1) (4)
  
  1. Universit茅 de Poitiers ; CNRS鈥揢MR 6008 ; Laboratoire de Chimie et Microbiologie de l鈥橢au ; ENSIP ; 86022 ; Poitiers ; France
  2. Universit茅 Paris-Est ; Leesu (UMR-MA-102) ; UPEC ; ENPC ; AgroParisTech ; Cr茅teil ; 94010 ; Paris ; France
  3. Universit茅 de Bordeaux ; CNRS ; UMR 5805 ; EPOC-Laboratoire de Physico et Toxico Chimie de l鈥橢nvironnement ; Talence ; 33405 ; Bordeaux ; France
  4. Water Desalination and Reuse Center ; King Abdullah University of Science and Technology (KAUST) ; Thuwal ; Saudi Arabia
  
• 关键词：Trifluralin ; Dissolved organic matter ; K DOM partition coefficient ; SPME
• 刊名：Environmental Science and Pollution Research
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：22
• 期：6
• 页码：4201-4212
• 全文大小：367 KB
• 参考文献：Water quality鈥攑rotocol for the initial method performance assessment in a laboratory. Association Fran莽aise de Normalisation (AFNOR), France
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• 刊物类别：Earth and Environmental Science
• 刊物主题：Environment
  Environment
  Atmospheric Protection, Air Quality Control and Air Pollution
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Industrial Pollution Prevention
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1614-7499

文摘

Solid-phase microextraction (SPME) was used to determine the equilibrium association constant for a pesticide, trifluralin (TFR), with dissolved organic matter (DOM). After optimization of the SPME method for the analysis of TFR, partition coefficients (K DOM) with three different sources of DOM were determined in buffered solutions at pH 7. Commercial humic acids and DOM fractions isolated from two surface waters were used. The values of log K DOM varied from 4.3 to 5.8, depending on the nature of the organic material. A good correlation was established between log K DOM and DOM properties (as measured with the H/O atomic ratio and UV absorbance), in agreement with literature data. This is consistent with the effect of polarity and aromaticity for governing DOM-pollutant associations, regardless of the origin of DOM. This association phenomenon is relevant to better understand the behavior of pesticides in the environment since it controls part of pesticide leaching and fate in aquatic systems.