Magnetron formation of Ni/YSZ anodes of solid oxide fuel cells

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• 作者：A. A. Solov’ev (1)
  N. S. Sochugov (1)
  I. V. Ionov (2)
  A. V. Shipilova (2)
  A. N. Koval’chuk (1)
  
• 关键词：magnetron sputtering ; solid oxide fuel cell ; Ni/YSZ anode ; cermet ; porous nanocomposite
• 刊名：Russian Journal of Electrochemistry
• 出版年：2014
• 出版时间：July 2014
• 年：2014
• 卷：50
• 期：7
• 页码：647-655
• 全文大小：2,486 KB
• 参考文献：1. Williams, M.C., / Fuel Cells, 2001, vol. 1, p. 87. CrossRef
  2. Bobrenok, O.F. and Predtechenskii, M.R., / Russ. J. Electrochem., 2010, vol. 46, p. 798. CrossRef
  3. Beckel, D., Bieberle-Hutter, A., Harvey, A., Infortuna, A., Muecke, U.P., Prestat, M., Rupp, J.L.M., and Gauckler, L.J., / J. Power Sources, 2007, vol. 173, p. 325. CrossRef
  4. Kim, Y.B., Park, J.S., Gur, T.M., and Prinz, F.B., / J. Power Sources, 2011, vol. 196, p. 10550. CrossRef
  5. Su, P.C., Chao, C.C., Shim, J.H., Fasching, R., and Prinz, F.B., / Nano Lett., 2008, vol. 8, p. 2289. CrossRef
  6. Sochugov, N.S., Soloviev, A.A., Shipilova, A.V., and Rotshtain, V.P., / Int. J. Hydrogen Energy, 2011, vol. 36, no. 9, p. 5550. CrossRef
  7. Costamagna, P., Costa, P., and Antonucci, V., / Electrochim. Acta, 1998, vol. 43, p. 375. CrossRef
  8. Muecke, U.P., Beckel, D., Bernard, A., Bieberle-Hutter, A., Graf, S., Infortuna, A., Muller, P., Rupp, J.L.M., Schneider, J., and Gauckler, L.J., / Adv. Funct. Mater., 2008, vol. 18, p. 31. CrossRef
  9. Muecke, U.P., Graf, S., Rhyner, U., and Gauckler, L.J., / Acta Materialia, 2008, vol. 56, p. 677. CrossRef
  10. Pratihar, S.K., Dassharma, A., and Maiti, H.S., / J. Mater. Sci., 2007, vol. 42, p. 7220. CrossRef
  11. Noh, H., Park, J., Son, J., Lee, H., Lee, J., and Lee, H., / J. Am. Ceram. Soc., 2009, vol. 92, no. 12, p. 3064. CrossRef
  12. Meng, B., Sun, Y., He, X.D., and Li, M.W., / Mater. Sci. Technol., 2008, vol. 24, no. 8, p. 997. CrossRef
  13. Jou, Sh. and Wu, Tz.-H., / J. Phys. Chem. Solids, 2008, vol. 69, p. 2804. CrossRef
  14. Rezugina, E., Thomann, A.L., Hidalgo, H., Brault, P., Dolique, V., and Tessier, Y., / Surf. Coat. Technol., 2010, vol. 204, p. 2376. CrossRef
  15. Movchan, B.A. and Lemkey, F.D., / Surf. Coat. Technol, 2003, vol. 165, p. 90. CrossRef
  16. La, O.G.J., Hertz, J., Tuller, H., and Shao-Horn, Y., / J. Electroceramics, 2004, vol. 13, p. 691. CrossRef
  17. Hertz, J.L. and Tuller, H.L., / J. Electrochem. Soc., 2007, vol. 154, no. 4, p. 413. CrossRef
  18. Hayashi, K., Yamamoto, O., Nishigaki, Y., and Ninoura, H., / Denki Kagaku, 1996, vol. 64, no. 10, p. 1097.
  19. Wang, L.S. and Barnett, S.A., / Solid State Ionics, 1995, vol. 76, p. 103. CrossRef
  20. Kukla, R., / Surf. Coat. Technol., 1997, vol. 93, p. 1. CrossRef
  21. Solov’ev, A.A., Sochugov, N.S., Ionov, I.V., Kirdyashkin, A.I., Kitler, V.D., Maznoi, A.S., Maksimov, Yu.M., and Sigfusson, T.I., / Perspekt. Mater., 2013, no. 4, p. 31.
  22. Solov’ev, A.A., Sochugov, N.S., Shipilova, A.V., Efimova, K.B., and Tumashevskaya, A.E., / Russ. J. Electrochem., 2011, vol. 47, no. 4, p. 494. CrossRef
  23. Hotovy, I., Huran, J., Spiess, L., Liday, J., Sitter, H., and Hascik, S., / Vacuum, 2003, vol. 69, p. 237. CrossRef
  24. Scardi, P., Polonioli, P., and Ferrari, S., / Thin Solid Films, 1994, vol. 253, p. 349. CrossRef
  25. Jou, S., Yeh, D.Y., and Tseng, A.A., / J. Nanosci. Nanotechnol., 2008, vol. 8, p. 390. CrossRef
  26. Klement, U., Erb, U., El-Sherik, A.M., and Aust, K.T., / Mater. Sci. Eng., A, 1995, vol. 203, p. 177. CrossRef
  27. Knauth, P., Charai, A., and Gas, P., / Scr. Metall. Mater., 1993, vol. 28, p. 325. CrossRef
  28. Holzera, L., Iwanschitz, B., Hocker, Th., Munch, B., Prestat, M., Wiedenmann, D., Vogt, U., Holtappels, P., Sfeir, J., Mai, A., and Graule, Th., / J. Power Sources, 2011, vol. 196, p. 1279. CrossRef
  29. Gubner, A., Landes, H., Metzger, J., Seeg, H., and Stübner, R., / Proc. 192nd Meeting of the Electrochemical Society, ECS, Paris, 1997, p. 844.
  30. Vassen, R., Simwonis, D., and Stover, D., / J. Mater. Sci., 2001, vol. 36, p. 147. CrossRef
  31. Noh, H.S., Son, J.W., Lee, H., Ji, H.I., Lee, J.H., and Lee, H.W., / J. Eur. Ceram. Soc., 2010, vol. 30, p. 3415. CrossRef
  32. Jiang, S., / J. Power Sources, 2008, vol. 183, no. 2, p. 595. CrossRef
  
• 作者单位：A. A. Solov’ev (1)
  N. S. Sochugov (1)
  I. V. Ionov (2)
  A. V. Shipilova (2)
  A. N. Koval’chuk (1)
  
  1. Tomsk Polytechnical University, pr. Lenina 30, Tomsk, 634050, Russia
  2. Institute of High Current Electronics, Siberian Branch, Russian Academy of Sciences, Akademicheskii pr. 2/3, Tomsk, 634055, Russia
  
• ISSN：1608-3342

文摘

Physico-chemical and structural properties of nanocomposite NiO/ZrO2:Y2O3 (NiO/YSZ) films applied using the reactive magnetron deposition technique are studied for application as anodes of solid oxide fuel cells. The effect of oxygen consumption and magnetron power on the discharge parameters is determined to find the optimum conditions of reactive deposition. The conditions for deposition of NiO/YSZ films, under which the deposition rate is maximum (12 μm/h), are found and the volume content of Ni is within the range of 40-0%. Ni-YSZ films reduced in a hydrogen atmosphere at the temperature of 800°C have a nanoporous structure. However, massive nickel agglomerates are formed in the course of reduction on the film surface; their amount grows at an increase in Ni content in the film. Solid oxide fuel cells with YSZ supporting electrolyte and a LaSrMnO3 cathode are manufactured to study electrochemical properties of NiO/YSZ films. It is shown that fuel cells with a nanocomposite NiO/YSZ anode applied using a magnetron sputtering technique have the maximum power density twice higher than in the case of fuel cells with an anode formed using the high-temperature sintering technique owing to a more developed gas-anode-electrolyte three-phase boundary.