Synthesis and application of Amberlite xad-4 functionalized with alizarin red-s for preconcentration and adsorption of rhodium (III)

详细信息    查看全文

• 作者：Hossein Sid Kalal (1)
  Homayon Ahmad Panahi (2)
  Hassan Hoveidi (3)
  Mohammad Taghiof (1)
  Mahnaz Taheri Menderjani (2)
  
• 关键词：Environmental measurement ; Solid phase extraction ; Amberlite XAD ; 4 ; Rhodium ; Immobilization
• 刊名：Journal of Environmental Health Science and Engineering
• 出版年：2012
• 出版时间：December 2012
• 年：2012
• 卷：9
• 期：1
• 全文大小：347KB
• 参考文献：1. Marshall MA, Mottola HA: Synthesis of silica-immobilized 8-quinolinol with (aminophenyl)trimethoxysilane. / Anal Chem 1983, 55:2089-093. CrossRef
  2. Roldan PS, Alcantara IL, Castro GR, Rocha SC, Padilha CCF, Padilha PM: Determination of Cu, Ni, and Zn in fuel ethanol by FAAS after enrichment in column packed with 2-aminothiazole-modified silica gel. / Anal Bioanal Chem 2003, 375:574-77.
  3. Gurnani V, Singh AK, Venkataramani B: Cellulose based macromolecular chelator having pyrocatechol as an anchored ligand: synthesis and applications as metal extractant prior to their determination by flame atomic absorption spectrometry. / Talanta 2003,61(15):889-03. CrossRef
  4. Gurnani V, Singh AK, Venkataramani B: Cellulose functionalized with 8-hydroxyquinoline: new method of synthesis and applications as a solid phase extractant in the determination of metal. / Anal Chim Acta 2003, 485:221-32. CrossRef
  5. Dmitrienko SG, Sviridova OA, Pyatkova LN, Senyavin VM: On the new approach to the theory of preferential wetting of heterogeneous solid surfaces. / Anal Bioanal Chem 2002, 374:361-68. CrossRef
  6. Gal PK, Patel S, Mshra BK: Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. / Talanta 2004, 62:1005-028. CrossRef
  7. Valkenberg MH, Holderich WF: Preparation and use of hybrid organic inorganic catalyst. / Cat Rev 2002, 44:321-74. CrossRef
  8. Price PM, Clark JH, Macquarrie DJ: Modified Silicas for Clean Technology. / J Chem Soc Dalton Trans 2000, 1:101. CrossRef
  9. Simpson NJK (Ed): / Solid Phase Extraction, Principles, Techniques and Applications. New York: Marcel Dekker; 2000.
  10. Camel V: Solid phase extraction of trace elements. / Spectrochim Acta part B 2003, 58:1177-233. CrossRef
  11. Gaur N, Dhankhar R: equilibrium modelling and spectroscopic studies for the biosorption of zn+2 ions from aqueous solution using immobilized spirulinaplatensis. / Iran J Environ Health Sci Eng 2009, 6:1-.
  12. Ghadiri SK, Nabizadeh R, Mahvi AH, Nasseri S, Kazemian H, Mesdaghinia AR, Nazmara S: methyltert-butyl ether adsorption on surfactant modified natural zeolites. / Iran J Environ Health Sci Eng 2010, 7:241-52.
  13. Ehrampoush MH, Ghanizadeh G, Ghaneian MT: equilibrium and kinetics study of reactive red 123 dyeremoval from aqueous solution by adsorption on eggshell. / Iran J Environ Health Sci Eng 2011, 8:101-08.
  14. Tewari PK, Singh AK: Amberlite XAD-2 functionalized with chromotropic acid: synthesis of a new polymer matrix and its applications in metal ion enrichment for their determination by flame atomic absorption spectrometry. / Analyst 1999, 120:1847-851. CrossRef
  15. Lemos VA, Baliza PX, Santos JS: Synthesis of α-Nitroso-β-Naphthol Modified Amberlite XAD-2 Resin and its Application in On-Line Solid Phase Extraction System for Cobalt Preconcentration. / Sep Sci Technol 2004, 39:3317-330. CrossRef
  16. Saxena R, Singh AK, Rathore DPS: Salicylic Acid Functionalised Polystyrene sorbent Amberlite XAD-2: Synthesis and Applications as a preconcentrator in the Determination of Zinc(II) and Lead(II) by Atomic Absorption Spectrophotometry. / Analyst 1995, 120:403-05. CrossRef
  17. Tewari PK, Singh AK: Synthesis, characterization and applications of pyrocatechol modified amberlite XAD-2 resin for preconcentration and determination of metal ions in water samples by flame atomic absorption spectrometry (FAAS). / Talanta 2001, 53:823-33. CrossRef
  18. Narin I, Soylak M, Kayakirilmaz K, Elci L, Dogan M: Preparation of a Chelating Resin by Immobilizing 1-(2-Pyridylazo) 2-Naphtol on Amberlite XAD-16 and its Application of Solid Phase Extraction of Ni(II), Cd(II), Co(II), Cu(II), Pb(II) and Cr(III) in Natural Water Samples. / Anal Lett 2003, 36:641-58. CrossRef
  19. ?eki? SD, Filik H, Apak R: Use of o-aminobenzoic acid functionalized XAD-4 copolymer resin for the separation and preconcentration of heavy metal (II) ions. / Anal Chim Acta 2004, 505:15-4. CrossRef
  20. Guo Y, Din B, Liu Y, Chang X, Meng S, Tian M: Preconcentration of trace metals with 2-(methylthio) aniline-functionalized XAD-2 and their determination by flame atomic absorption spectrometry. / Anal Chim Acta 2004, 504:319-24. CrossRef
  21. Lemos VA, Baliza PX, Yamaki RT, Rocha ME, Alves APO: Synthesis and application of a functionalized resinin on-line system for copper preconcentration and determination infoods by flame atomic absorption spectrometry. / Talanta 2003, 61:675-82. CrossRef
  22. Lemos VA, Baliza PX: Amberlite XAD-2 Functionalized with 2-Ami- nothiophenol as a New Sorbent for On-line Preconcentration of Cad- mium and Copper. / Talanta 2005, 67:564-70. CrossRef
  23. Metilda P, Sanghamitra K, Mary Gladis J, Naidu GRK, PrasadaRao T: Succinic acid functionalized Amberlite XAD-4 sorbent for the solid phase extractive preconcentration and separation of uranium (VI). / Talanta 2005, 65:192-00.
  24. Tewari PK, Singh AK: Preconcentration of lead with Amberlite XAD-2 and Amberlite XAD-7based chelating resins for its determination by flame atomic absorption spectrometry. / Talanta 2002, 56:735-44. CrossRef
  25. Saxena R, Singh AK, Sambi SS: Synthesis of a chelating polymer metrix by immobilizing alizarin red –S Amberlite XAD-2 and its application to the preconcentration of Lead (II), cadmium (II), zink(II) and nickel (II). / Anal Chim Acta 1994, 295:199-04. CrossRef
  26. Lemos VA, Baliza PX, Santos JS, Nunes LS, Sesus AA, Rocha ME: A new functionalized resin and its application in preconcentration system with multivariate optimization for nickel determination in food samples. / Talanta 2005, 66:174-80. CrossRef
  27. Dev K, Pathak R, Rao GN: Sorption behaviour of lanthanum (III), neodymium (III), therbium (III), thorium (III) and uranium (VI) on Amberlite XAD-4 resin funcionazed with bicines ligands. / Talanta 1999, 48:579-84. CrossRef
  28. Prabhakaran D, Subramanian MS: A new chelating sorbent for metal ion extraction under high saline conditions. / Talanta 2003, 59:1227-236. CrossRef
  29. Brajter K, OlbrychSleszynska E, Staskiewicz M: Preconcentration and Separation of Metal Ions by Means of Amberlite XAD-2 Loaded with Pyrocatechol Violet. / Talanta 1988, 35:65-7. CrossRef
  30. Abollino O, Mentasti E, Porta V, Sarzanini C: Immobilized 8-oxine units on different solid sorbents for the uptake of metal traces. / Anal Chem 1990, 62:21-6. CrossRef
  31. Blain S, Appriou P, Handel H: Column Preconcentration of Trace Metals from Sea-Water with Macroporous Resins Impregnated with Lipophilic TetraazaMacrocycles. / Analyst 1991, 116:815-20. CrossRef
  32. Saxena R, Singh AK: Pyrocatechol Violet immobilized Amberlite XAD-2: synthesis and metal-ion uptake properties suitable for analytical applications. / Anal Chim Acta 1997, 340:285-90. CrossRef
  33. Jain VK, Sait SS, Shrivastav P, Agrawal YK: Application of chelate forming resin Amberlite XAD-2-o-vanillinthiosemicarbazone to the separation and preconcentration of copper(II), zinc(II) and lead(II). / Talanta 1997, 51:397-04. CrossRef
  34. Abollino O, Aceto M, Bruzzoniti MC, Mentasti E, Sarzanini C: Determination of metals in highly saline matrices by solid-phase extraction and slurry-sampling inductively coupled plasma-atomic emission spectrometry. / Anal Chim Acta 1998, 375:293-98. CrossRef
  35. Kumar M, Rathore DPS, Singh AK: Amberlite XAD-2 Functionlized with o-Aminophenol: Synthesis and Applications as Extractant for Copper(II), Cobalt(II), Cadmium(II), Nickel(II), Zinc(II) and Lead(II). / Talanta 2000, 51:1187-196. CrossRef
  36. Kumar M, Rathore DPS, Singh AK: Metal Ion Enrichment on Amberlite XAD-2 Functionalized with Tiron: Analytical Applications. / Analyst 2000, 125:1221-226. CrossRef
  37. Tewari PK, Singh AK: Thiosalicylic acid-immobilized Amberlite XAD-2: metal sorption behaviour and applications in estimation of metal ions by flame atomic absorption spectrometry. / Analyst 2000, 125:2350-355. CrossRef
  38. Hall KR, Eagleton LC, Acrivos A, Vermeulen T: Pore-and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern condition. / Ind Eng Chem Fundam 1966,5(2):212-23. CrossRef
  39. Ho YS, Ofomaja AE: Biosorption thermodynamics of cadmium on coconut copra meal as biosorbent. / Biochem Eng J 2006, 30:117-23. CrossRef
  40. Gomathi Devi L, Rajashekhar KE, AnanthaRaju KS, Girish Kumar S: Kinetic modeling based on the non-linear regression analysis for the degradation of Alizarin Red S by advanced photo Fenton process using zero valent metallic iron as the catalyst Journal of Molecular Catalysis A. / Chemical 2009, 314:88-4.
  
• 作者单位：Hossein Sid Kalal (1)
  Homayon Ahmad Panahi (2)
  Hassan Hoveidi (3)
  Mohammad Taghiof (1)
  Mahnaz Taheri Menderjani (2)
  
  1. Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, Atomic Energy Organization of Iran, Tehran, Iran
  2. Department of Chemistry, Central Tehran Islamic Azad University, Tehran, Iran
  3. Graduate Faculty of Environment, University of Tehran, Tehran, Iran
  
• ISSN：2052-336X

文摘

A new chelating resin was prepared by coupling Amberlite XAD-4 with alizarin red-s through an azo spacer, characterized by infra-red spectroscopy and thermal analysis and studied for Rh(III) preconcentration using inductively coupled plasma atomic emission spectroscopy (ICP-AES) for rhodium monitoring in the environment. The optimum pH for sorption of the metal ion was 6.5. The sorption capacity was found 2.1 mg/g of resin for Rh(III). A recovery of 88% was obtained for the metal ion with 1.5 M HCl as eluting agent. Kinetic adsorption data were analyzed by adsorption and desorption times of Rh(III) on modified resin. Scat chard analysis revealed that the homogeneous binding sites were formed in the polymers. The linear regression equation was Q/C-?-.3169Q--7.222 (R2--.9239), for Rh were formed in the SPE sorbent,Kd and Qmax for the affinity binding sites were calculated to be 0.76 μmol/mL and 20.67 μmol/g, respectively. The equilibrium data and parameters of Rh(III) adsorption on modified resin were analyzed by Langmuir, Freundlich, Temkin and Redlich–Peterson models. The experimental adsorption isotherm was in good concordance with Langmuir and Freundlich models (R2-gt;-.998) and based on the Langmuir isotherm the maximum amount of adsorption (qmax) was 4.842 mg/g. The method was applied for rhodium ions determination in environmental samples. with high recovery (>80%).