Annulated Mesoporous Silica as Potent Lanthanide Ion Adsorbents and Magnetic Resonance Contrast Enhancing Agents

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• 作者：Shao-Chun Wang ; Yu-Shen Hsu ; Chia-Teng Hsiao…
• 关键词：Mesoporous silica ; Functionalization ; SBA ; 15 ; MRI contrast agent ; Lanthanide
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：26
• 期：1
• 页码：165-171
• 全文大小：3,405 KB
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• 作者单位：Shao-Chun Wang (1)
  Yu-Shen Hsu (1)
  Chia-Teng Hsiao (1)
  Chang-Cheng Wu (1)
  Yu-Chein Sue (1)
  Saad M. Alshehri (2)
  Tansir Ahamad (2)
  Yusuke Yamauchi (2) (3)
  Jeffrey E. Chen (4)
  Kevin C.-W. Wu (4)
  Fa-Kuen Shieh (1)
  
  1. Department of Chemistry, National Central University, Taoyuan, 32001, Taiwan
  2. Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia
  3. World Premier International (WPI) Research Centre for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan
  4. Department of Chemical Engineering, National Taiwan University, Taipei, 10617, Taiwan
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451

文摘

We report a series of SBA-15 type mesoporous silica (MS) possessing functional annulated rings of different sizes obtained by post-synthesis grafting with diamines containing backbones and different numbers of carbon atoms as efficient magnetic resonance imaging (MRI) contrasting agents. Interestingly, lanthanide ion adsorption assays in aqueous solutions of pH 7 at room temperature showed that adsorption efficiency was higher for materials with rings than those without rings. Furthermore, annulated MS synthesized with 1,5-diaminopetane exhibited selective chelation with smaller Yb(III) ions owing to the “macrocyclic effect” of the cation cavity that offers a “best fit.” Additionally, Gd(III) ions chelated with the material modified by 1, 5-diaminopetane denoted as Gd@annulated-MS exhibited high r2/r1 relaxivities of 12, 12, and 28 while measured with 7.0 T (300 MHz), 9.4 T (400 MHz), and 11.4 T (500 MHz), respectively. Finally, the nanoscale parent materials for annulated modification were successfully synthesized for further in vivo applications. The MS materials thus obtained open auxiliary avenues for selective lanthanide ion absorption via manipulation of the annular ring size to be potentially applied in new generation MRI contrast agents. Keywords Mesoporous silica Functionalization SBA-15 MRI contrast agent Lanthanide