Effects of iso-and heterovalent substitutions on the luminescent properties of CdS in the systems Zn, Cd ?S, Te and In(III), Cd ?S, Te
文摘
We have studied the luminescent properties of three CdS-based solid-solution series, resulting from isovalent anion substitution (CdS1−x Tex), isovalent cation and anion substitutions (Cd1−x ZnxS1−x Tex), and heterovalent cation substitution in combination with isovalent anion substitution (Cd1−x In2x/3S1−x Tex). The last two systems have been studied for the first time. The results demonstrate that red or near-IR lumiescence occurs in the three systems, but CdS crystals codoped with In and Te are more attractive because of the high impurity-related emission intensity at rather low In and Te concentrations.