Effects of iso-and heterovalent substitutions on the luminescent properties of CdS in the systems Zn, Cd -S, Te and In(III), Cd -S, Te
文摘
We have studied the luminescent properties of three CdS-based solid-solution series, resulting from isovalent anion substitution (CdS1?x Tex), isovalent cation and anion substitutions (Cd1?x ZnxS1?x Tex), and heterovalent cation substitution in combination with isovalent anion substitution (Cd1?x In2x/3S1?x Tex). The last two systems have been studied for the first time. The results demonstrate that red or near-IR lumiescence occurs in the three systems, but CdS crystals codoped with In and Te are more attractive because of the high impurity-related emission intensity at rather low In and Te concentrations.