Binuclear cyanide-bridged cobalt–iron complexes

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• 作者：Guo ; Dong ; Zhan ; Shuzhong ; Yuan ; Chunwei
• 刊名：Transition Metal Chemistry
• 出版年：2000
• 出版时间：2000
• 年：2000
• 卷：25
• 期：3
• 页码：299-301
• 全文大小：75 KB

文摘

Three new binuclear complexes: [(NO)(CN)<math>_4math>FeCN–Co(en)<math>_2math>] · H<math>_2math>O (1), [(NO)(CN)<math>_4math>FeCN–Co(pn)<math>_2math>] · 2H<math>_2math>O (2), and [(NO)(CN)<math>_4math>FeCN–Co(tn)<math>_2math>] · 3H<math>_2math>O (3) (en = ethylenediamine, pn = 1,2-diaminopropane; tn = 1,3-diaminopropane) have been prepared and their properties studies by i.r., u.v. spectroscopy, cyclic voltammetry, and by magnetic measurements.