Syntheses and Characterization of Two Cd(II) Coordination Polymers Based on Mixed Flexible Ligands
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- 作者：Longcun Xu ; Baoyong Zhu
- 关键词：Cd(II) coordination polymers ; Structural diversification ; Photoluminescence
- 刊名：Journal of Inorganic and Organometallic Polymers and Materials
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：26
- 期：1
- 页码：264-269
- 全文大小：1,153 KB
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Baoyong Zhu (1)
1. Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong (Dezhou University), School of Chemistry and Chemical Engineering, Dezhou University, Dezhou, 253023, People’s Republic of China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Inorganic Chemistry
Organic Chemistry
Polymer Sciences - 出版者：Springer New York
- ISSN：1574-1451
文摘
Two new Cd(II) coordination polymers based on mixed flexible ligands, namely, {[Cd(dtsa)(bbi)]·DMF}n (1) and [Cd(dtsa)(bpp)]n (2) (H2dtsa = 2, 2′-dithiosalicylic acid, bbi = 1,1′-(1,4-butanediyl)bis(imidazole), bpp = 1,3-bi(4-pyridyl)propane), have been successfully constructed under solvothermal conditions. Complex 1 diplays a parallel threefold interpenetrating 2D layers with sql topology, and complex 2 is a 3D threefold interpenetrating architecture with bcu-x-4-P3212 topology. The photoluminescent spectra indicate that at room temperature, complexes 1 and 2 emit blue-purple luminescence. Keywords Cd(II) coordination polymers Structural diversification Photoluminescence