Synthesis of nanostructured CuInS2 thin films and their application in dye-sensitized solar cells
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  • 作者:Yu Zhao ; Fazhi Luo ; Mixue Zhuang ; Zhen Liu ; Aixiang Wei ; Jun Liu
  • 刊名:Applied Physics A: Materials Science & Processing
  • 出版年:2016
  • 出版时间:March 2016
  • 年:2016
  • 卷:122
  • 期:3
  • 全文大小:2,242 KB
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  • 作者单位:Yu Zhao (1)
    Fazhi Luo (1) (3)
    Mixue Zhuang (1)
    Zhen Liu (1)
    Aixiang Wei (1)
    Jun Liu (1) (2)

    1. Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Material and Energy, Guangdong University of Technology, Guangzhou, 510006, China
    3. The Fifth Electronics Research Institute of Ministry of Industry and Information Technology, Guangzhou, 510006, China
    2. State Key Lab of Silicon Materials, Zhejiang University, Hangzhou, 310027, China
  • 刊物类别:Physics and Astronomy
  • 刊物主题:Physics
    Condensed Matter
    Optical and Electronic Materials
    Nanotechnology
    Characterization and Evaluation Materials
    Surfaces and Interfaces and Thin Films
    Operating Procedures and Materials Treatment
  • 出版者:Springer Berlin / Heidelberg
  • ISSN:1432-0630
文摘
CuInS2 (CIS) nanostructure thin films were successfully synthesized on FTO conductive glass substrates by solvothermal method. It is found that the surface morphology and microstructure of CIS thin films can be tailored by simply adjusting the concentration of oxalic acid. CIS nanostructure films with texture of “nanosheet array” and “flower-like microsphere” were obtained and used as Pt-free counter electrode for dye-sensitized solar cells (DSSCs). The nanosheet array CIS was found to have a better electrocatalytic activity than the flower-like microsphere one. DSSCs based on nanosheet array CIS thin film counter electrode show conversion efficiency of 3.33 %, which is comparable to the Pt-catalyzed DSSCs. The easy synthesis, low cost, morphology tunable and excellent electrocatalytic property may make the CuInS2 nanostructure competitive as counter electrode in DSSCs.

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