Solvent-free reaction of 3-aryl-6-(3-nitrophenyl)-1,2,4-triazines with 4-(cyclohex-1-en-1-yl)morpholine

详细信息    查看全文

• 作者：D. S. Kopchuk ; A. F. Khasanov ; A. P. Krinochkin…
• 刊名：Russian Journal of Organic Chemistry
• 出版年：2016
• 出版时间：July 2016
• 年：2016
• 卷：52
• 期：7
• 页码：1036-1038
• 全文大小：232 KB
• 刊物主题：Organic Chemistry;
• 出版者：Springer US
• ISSN：1608-3393
• 卷排序：52

文摘

The aza-Diels–Alder reaction of 3-aryl-6-(3-nitrophenyl)-1,2,4-triazines with 4-(cyclohex-1-en-1-yl)morpholine as dienophile was accompanied by reduction of the nitro group to amino. In the reaction of 3-(4-methoxyphenyl)-6-(3-nitrophenyl)-1,2,4-triazine with 4-(cyclohex-1-en-1-yl)morpholine, 3-[3-(4-methoxyphenyl)-1,2,4-triazin-6-yl)aniline was formed together with the cycloaddition product.