Self-Healing Polymers Based on Reversible Covalent Bonds

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• 关键词：Diels–Alder reaction ; Disulfide bonds ; Intrinsic self ; healing polymers ; Radicals ; Reversible addition reactions ; Reversible covalent bonds ; Self ; healing polymers
• 刊名：Advances in Polymer Science
• 出版年：2016
• 出版时间：2016
• 年：2016
• 卷：273
• 期：1
• 页码：1-58
• 全文大小：3,459 KB
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• 作者单位：Natascha Kuhl (22) (23)
  Stefan Bode (22) (23)
  Martin D. Hager (22) (23)
  Ulrich S. Schubert (22) (23)
  
  22. Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstrasse 10, 07743, Jena, Germany
  23. Jena Center of Soft Mater (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, 07743, Jena, Germany
  
• 丛书名：Self-healing Materials
• ISBN：978-3-319-32778-5
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1436-5030
• 卷排序：273

文摘

Starting with reversible polymer networks based on the Diels–Alder reaction of furan and maleimide, a large variety of different self-healing polymers based on reversible covalent interactions have been developed in the last decade. These intrinsic self-healing polymers are mainly based on reversible addition reactions, exchange reactions, and condensations. The most prominent examples of such materials are based on Diels–Alder chemistry, photocycloadditions, disulfide reactions, acylhydrazones, and reversible radical reactions.