Water-soluble graphene dispersion functionalized by Diels–Alder cycloaddition reaction
详细信息 查看全文
- 作者：Jie Zhang ; Wenyuan Wang ; Hua Peng ; Jiangtao Qian…
- 关键词：Functional graphene ; Furfuryl alcohol ; Diels–Alder cycloaddition reaction
- 刊名：Journal of the Iranian Chemical Society
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：14
- 期：1
- 页码：89-93
- 全文大小：
- 刊物主题：Analytical Chemistry; Inorganic Chemistry; Physical Chemistry; Biochemistry, general; Organic Chemistry;
- 出版者：Springer Berlin Heidelberg
- ISSN：1735-2428
- 卷排序：14
文摘
Water-soluble graphene dispersions were fabricated by the exfoliation of graphite functionalized with furfuryl alcohol by Diels–Alder cycloaddition reaction. The pristine graphite was firstly heat-treated in N-methyl-2-pyrrolidone (NMP) before it was functionalized with furfuryl alcohol, and then, the increased interlayer spacing is propitious for furfuryl alcohol to enter into the lattice and react with graphite. High-resolution transmission electron microscopy and Raman spectroscopy indicate that the functional graphene is a high-quality product without any significant defects, and atomic force microscopy shows that the functional graphene consists of single to few layers graphene. Moreover, the grafting ratio onto graphene is up to 1.52 mmol/g. Therefore, the method provides a feasible route to produce functional graphene.