Polymer-coated magnetic nanospheres for preconcentration of organochlorine and pyrethroid pesticides prior to their determination by gas chromatography with electron capture detection
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- 作者：Genggeng Yang ; Zeying He ; Xueke Liu ; Chang Liu ; Jing Zhan ; Donghui Liu…
- 关键词：Magnetite nanoparticles ; Oleate coating ; Miniemulsion polymerization ; Copolymerization ; Plackett–Burman design ; Box–Behnken design ; Transmission electron microscopy ; Fourier transform infrared spectrometry
- 刊名：Microchimica Acta
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：183
- 期：3
- 页码：1187-1194
- 全文大小：684 KB
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Zeying He (1)
Xueke Liu (1)
Chang Liu (1)
Jing Zhan (1)
Donghui Liu (1)
Peng Wang (1)
Zhiqiang Zhou (1) (2)
1. Beijing Advanced Innovation Center for Food Nutrition and Human Health, Department of Applied Chemistry, China Agricultural University, Beijing, 100193, People’s Republic of China
2. Department of Applied Chemistry, China Agricultural University, No.2 Yuanmingyuan West Road, Beijing, 100193, People’s Republic of China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Analytical Chemistry
Inorganic Chemistry
Physical Chemistry
Characterization and Evaluation Materials
Monitoring, Environmental Analysis and Environmental Ecotoxicology - 出版者：Springer Wien
- ISSN：1436-5073
文摘
Magnetic polymer nanospheres were prepared and used as adsorbents for the extraction of organochlorine and pyrethroid pesticides from water samples. The adsorbents were synthesized by miniemulsion polymerization of N-vinylimidazole and divinylbenzene and simultaneous encapsulation of oleic acid-coated Fe3O4 nanoparticles. Following desorption with ethyl acetate, the target analytes β-hexachlorocyclohexane, δ-hexachlorocyclohexane, p,p’-DDE, heptachlor, trans-chlordan, cis-chlordan, bifenthrin, β-cypermethrin, δ-methrin, λ-cyhalothrin and esfenvalerate were determined by gas chromatography with electron capture detection. Desorption conditions, extraction times and sample volume were screened by Plackett-Burman design and optimized by Box-Behnken design. Under the optimum conditions, the organochlorines can be quantified in the 20 to 400 ng L−1 concentration range, and the pyrethroids in the 400 to 4000 ng L−1 concentration range. The recoveries of organochlorines and pyrethroids from spiked real water samples are between 77.6 and 97.3 %, with relative standard deviations between 0.9 and 10.0 %. The method for magnetic solid phase extraction described here is fast, simple and friendly to the environment.