Regulating effect of hemicelluloses on the preparation and properties of composite Lyocell fibers

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• 作者：Jing-Huan Chen ; Ying Guan ; Kun Wang ; Feng Xu ; Run-Cang Sun
• 关键词：Composite Lyocell fiber ; Regulating effect ; Bamboo hemicelluloses ; Cellulose
• 刊名：Cellulose
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：22
• 期：3
• 页码：1505-1516
• 全文大小：2,254 KB
• 参考文献：Andersson S, Serimaa R, Paakkari T, Saranp脛脛 P, Pesonen E (2003) Crystallinity of wood and the size of cellulose crystallites in Norway spruce (Picea abies). J Wood Sci 49:531鈥?37
  Azubuike CP, Rodr铆guez H, Okhamafe AO, Rogers RD (2012) Physicochemical properties of maize cob cellulose powders reconstituted from ionic liquid solution. Cellulose 19(2):425鈥?33View Article
  Biganska O, Navard P (2005) Kinetics of precipitation of cellulose from cellulose-NMMO-water solutions. Biomacromolecules 6:1948鈥?953View Article
  Chundawat SP, Bellesia G, Uppugundla N, Sousa LC, Gao D, Cheh AM, Agarwal UP, Bianchetti CM, Phillips GN, Langan P, Balan V, Gnanakaran S, Dale BE (2011) Restructuring the crystalline cellulose hydrogen bond network enhances its depolymerization rate. J Am Chem Soc 133:11163鈥?1174View Article
  Cross CF, Bevan EJ, Beadle C (1892) Viscose syndicate. British Patent 8700
  Dunstan DE, Hill EK, Wei YL (2004) Direct measurement of polymer segment orientation and distortion in shear: semi-dilute solution behavior. Polymer 45:1261鈥?266View Article
  El-Kafrawy A (1982) Investigation of the cellulose/LiCl/dimethylacetamide and cellulose/LiCl/N-methyl-2-pyrrolidinone solutions by 13C NMR spectroscopy. J Appl Polym Sci 27:2435鈥?443View Article
  Fink HP, Weigel P, Purz H, Ganster J (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26:1473鈥?524View Article
  French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885鈥?96View Article
  French AD, Santiago Cintr蠈n M (2013) Cellulose polymorphy, crystallite size, and the segal crystallinity index. Cellulose 20:583鈥?88View Article
  Haward SJ, Sharma V, Butts CP, McKinley GH, Rahatekar SS (2012) Shear and extensional rheology of cellulose/ionic liquid solutions. Biomacromolecules 13:1688鈥?699View Article
  Jiang G, Huang W, Li L, Wang X, Pang F, Zhang Y, Wang H (2012a) Structure and properties of regenerated cellulose fibers from different technology processes. Carbohydr Polym 87:2012鈥?018View Article
  Jiang G, Yuan Y, Wang B, Yin X, Mukuze KS, Huang W, Zhang Y, Wang H (2012b) Analysis of regenerated cellulose fibers with ionic liquids as a solvent as spinning speed is increased. Cellulose 19:1075鈥?083View Article
  Khajavi R, Esfahani EJ, Sattari M (2011) Crystalline structure of microbial cellulose compared with native and regenerated cellulose. Int J Polym Mater 60:1178鈥?192View Article
  Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Edit 44:3358鈥?393View Article
  Langan P, Nishiyama Y, Chanzy H (2001) X-ray structure of mercerized cellulose II at 1 a resolution. Biomacromolecules 2:410鈥?16View Article
  Lennholm H, Larsson T, Iversen T (1994) Determination of cellulose I伪 and I尾 in lignocellulosic materials. Carbohyd Res 261:119鈥?31View Article
  Loerbroks C, Rinaldi R, Thiel W (2013) The electronic nature of the 1,4鈥揼lycosidic bond and its chemical environment: DFT insights into cellulose chemistry. Chem Eur J 19:16282鈥?6294View Article
  Moigne N, Navard P (2010) Dissolution mechanisms of wood cellulose fibres in NaOH鈥搘ater. Cellulose 17:31鈥?5View Article
  Nishiyama Y, Langan P, Chanzy H (2002) Crystal structure and hydrogen-bonding system in cellulose I尾 from synchrotron X-ray and neutron fiber diffraction. J Am Chem Soc 124:9074鈥?082View Article
  Ohlrogge J, Allen D, Berguson B, DellaPenna D, Shachar-Hill Y, Stymne S (2009) Driving on biomass. Science 324:1019鈥?020View Article
  Olsson C, Westman G (2013) Wet spinning of cellulose from ionic liquid solutions-viscometry and mechanical performance. J Appl Polym Sci 127:4542鈥?548View Article
  O鈥檚ullivan AC (1997) Cellulose: the structure slowly unravels. Cellulose 4:173鈥?07View Article
  Rubin EM (2008) Genomics of cellulosic biofuels. Nature 454:841鈥?45View Article
  Schild G, Sixta H (2011) Sulfur-free dissolving pulps and their application for viscose and lyocell. Cellulose 18:1113鈥?128View Article
  Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786鈥?94View Article
  Shi Z, Yang Q, Cai J, Kuga S, Matsumoto Y (2014) Effects of lignin and hemicellulose contents on dissolution of wood pulp in aqueous NaOH/urea solution. Cellulose 21:1205鈥?215View Article
  Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellulose with ionic liquids. J Am Chem Soc 124:4974鈥?975View Article
  Tian C, Zheng LQ, Miao QX, Cao CY, Ni YH (2014) Improving the reactivity of kraft-based dissolving pulp for viscose rayon production by mechanical treatments. Cellulose 21:3647鈥?654View Article
  Uddin AJ, Yamamoto A, Gotoh Y, Nagura M (2010) Preparation and physical properties of regenerated cellulose fibres from sugarcane bagasse. Text Res J 80:1846鈥?858View Article
  Wada M, Chanzy H, Nishiyama Y, Langan P (2004) Cellulose IIII crystal structure and hydrogen bonding by synchrotron X-ray and neutron fiber diffraction. Macromolecules 37:8548鈥?555View Article
  Wada M, Heux L, Nishiyama Y, Langan P (2009) X-ray crystallographic, scanning microprobe X-ray diffraction, and cross-polarized/magic angle spinning 13C NMR studies of the structure of cellulose IIIII. Biomacromolecules 10:302鈥?09View Article
  Wan J, Wang Y, Xiao Q (2010) Effects of hemicellulose removal on cellulose fiber structure and recycling characteristics of eucalyptus pulp. Bioresour Technol 101:4577鈥?583View Article
  Wang K, Jiang JX, Xu F, Sun RC (2009) Influence of steaming explosion time on the physic-chemical properties of cellulose from Lespedeza stalks (Lespedeza crytobotrya). Bioresour Technol 100:5288鈥?294View Article
  Wang H, Gurau G, Rogers RD (2012a) Ionic liquid processing of cellulose. Chem Soc Rev 41:1519鈥?537View Article
  Wang K, Yang H, Yao X, Xu F, Sun RC (2012b) Structural transformation of hemicelluloses and lignin from triploid poplar during acid-pretreatment based biorefinery process. Bioresour Technol 116:99鈥?06View Article
  Wang K, Yang H, Chen Q, Sun RC (2013) Influence of delignification efficiency with alkaline peroxide on the digestibility of furfural residues for bioethanol production. Bioresour Technol 146:208鈥?14View Article
  Wendler F, Todi L-N, Meister F (2012) Thermostability of imidazolium ionic liquids as direct solvents for cellulose. Thermochim Acta 528:76鈥?4View Article
  Zhang H, Tong M (2007) Influence of hemicelluloses on the structure and properties of Lyocell fibers. Polym Eng Sci 47:702鈥?06View Article
  Zhang H, Zhang H, Tong M, Shao H, Hu X (2008) Comparison of the structures and properties of Lyocell fibers from high hemicellulose pulp and high 伪-cellulose pulp. J Appl Polym Sci 107:636鈥?41View Article
  Zhou JP, Zhang LN (2000) Solubility of cellulose in NaOH/urea aqueous solution. Polym J 32:866鈥?70View Article
  
• 作者单位：Jing-Huan Chen (1)
  Ying Guan (1)
  Kun Wang (1)
  Feng Xu (1)
  Run-Cang Sun (1)
  
  1. Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing, 100083, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Bioorganic Chemistry
  Physical Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer Netherlands
• ISSN：1572-882X

文摘

Composite Lyocell fibers were successfully prepared from cotton linter pulp and bamboo hemicelluloses with N-methyl-morpholine-N-oxide as a solvent. The viscosity of the spinning solutions, as well as the structural and mechanical properties of the composite fibers were investigated to understand the effect of hemicelluloses on the dissolution process and the properties of fibers. The addition of hemicelluloses raised the concentration of spinning dopes and reduced the average molecular weight of raw materials, leading to the increase and then decrease of the viscosity of solution. The crystal and morphological structure of the fibers were slightly influenced by the presence of hemicelluloses, while the tensile strength and modulus of the fibers were improved by adding appropriate amount of hemicelluloses. Moreover, the distribution of hemicelluloses in the solution and composite fiber were proposed to illustrate this regulating effect. This study provided an alternate way to improve the properties of Lyocell fibers and enlarge the utilization of hemicelluloses.