Structures and Luminescent Properties of Two 2D Coordination Polymers Containing Tb(III) or Dy(III) Ions
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- 作者：Xiaoping An (1)
Hongsheng Wang (2)
Gongchun Li (2) - 关键词：2 ; 4 ; pyridinedicarboxylic acid ; Photoluminescence ; Oxalate ; Terbium ; Dysprosium
- 刊名：Journal of Fluorescence
- 出版年：2014
- 出版时间：March 2014
- 年：2014
- 卷：24
- 期：2
- 页码：425-429
- 全文大小：716 KB
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Hongsheng Wang (2)
Gongchun Li (2)
1. College of Animal Science, Inner Mongolia Agricultural University, Huhhot, Inner Mongolia, 010018, People’s Republic of China
2. School of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan, 461000, People’s Republic of China - ISSN：1573-4994
文摘
Two 2D rare earth terbium and dysprosium coordination polymers with 2,4-pyridinedicarboxylate and oxalate anions have been synthesized by hydrothermal method, the formula is {[RE(pda)(ox)0.5(H2O)4]·2H2O}n (RE = Tb (1) and Dy (2); H2pda = 2,4-pyridinedicarboxylic acid; ox = oxalate anion). The two complexes are isomorphic and crystallized in monoclinic system, P21/c space group. Each pda anion connects two rare earth ions with 2- carboxyl group and the nitrogen atom but the 4- carboxyl group does not coordinate with rare earth ions. Each ox anion connects two rare earth ions by μ 2-bridge way. Both the complexes exhibit intense characteristic luminescence of Tb(III) or Dy(III) ion with excitation of UV-rays.