Two new inorganic-organic hybrid compounds constructed from different polymolybdates and transition metal-amine subunits

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• 作者：Xiuli Wang ; Danna Liu ; Na Han ; Hongyan Lin…
• 关键词：Polyoxometalate ; Metal ; amine unit ; Crystal structure ; Electrochemical property ; Photocatalysis
• 刊名：Chemical Research in Chinese Universities
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：31
• 期：3
• 页码：337-341
• 全文大小：705 KB
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• 作者单位：Xiuli Wang (1)
  Danna Liu (1)
  Na Han (1)
  Hongyan Lin (1)
  Jian Luan (1)
  Aixiang Tian (1)
  
  1. Liaoning Province Silicon Materials Engineering Technology Research Centre, Department of Chemistry, Bohai University, Jinzhou, 121000, P. R. China
  
• 刊物主题：Chemistry/Food Science, general; Analytical Chemistry; Inorganic Chemistry; Organic Chemistry; Physical Chemistry;
• 出版者：Springer Berlin Heidelberg
• ISSN：2210-3171

文摘

Two new polyoxometalate(POM)-based hybrid compounds, [Cu(en)][H4Mo4O16]0.5(1)(en=ethylenediamine) and [Ag(3-C5H6N2)2][H2PMo12O40](2)(3-C5H6N2=3-aminopyridine), containing different transition metalamine subunits were hydrothermally synthesized and characterized by elemental analyses, infrared spectroscopy and single-crystal X-ray diffraction. For compound 1, each [H4Mo4O16]4(Mo4O16) cluster was linked to four neighboring Mo4O16 clusters through four [Cu(en)]2+ subunits to yield a (2,4)-connected 2D layer, which was further extended to a 3D supramolecular network via hydrogen bonding interactions. For compound 2, the adjacent [H2PMo12O40]-/sup> clusters were bridged by [Ag(3-C5H6N2)2]+ subunits to generate a 1D chain. The electrochemical behaviors and the photocatalytic activities of compounds 1 and 2 were studied in detail.