Competitive sorption and desorption of trace elements by Tunisian Aridisols Calcorthids

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• 作者：Hamdi Sahraoui ; María Luisa Andrade…
• 关键词：Competitive sorption/retention ; Trace elements ; Aridisol ; Sorption capacity ; Selective sequences ; Hysteresis
• 刊名：Environmental Science and Pollution Research
• 出版年：2015
• 出版时间：July 2015
• 年：2015
• 卷：22
• 期：14
• 页码：10861-10872
• 全文大小：687 KB
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• 作者单位：Hamdi Sahraoui (1) (2)
  María Luisa Andrade (1)
  Mohamed Hachicha (2)
  Flora Alonso Vega (1)
  
  1. Departamento de Bioloxía Vexetal e Ciencia do Solo, Facultade de Bioloxía, Universidade de Vigo, Lagoas, Marcosende, 36310, Vigo, Pontevedra, Spain
  2. Institut National de Recherche en Génie Rural Eaux et Forêts, Université de Carthage, Rue Hédi Elkarray, Elmenzah IV, Tunis, Tunisia
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：Environment
  Environment
  Atmospheric Protection, Air Quality Control and Air Pollution
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Industrial Pollution Prevention
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1614-7499

文摘

The sorption and retention processes play an important role in determining the bioavaibility and fate of trace elements in soils. Sorption and desorption of Pb2+, Zn2+, Ni2+, Cu2+, and Co2+ in three Tunisian Aridisols Calcorthids (AR1, AR2, and AR3) were studied using batch experiments. Sorption and retention capacities were determined by means of K r parameter and they were related to soil properties. The results showed that in all studied soils, K r values for Pb2+ and Cu2+ were higher than those of Zn2+, Ni2+, and Co2+ indicating that soils have higher affinity for the first ones. The high sorption and retention capacity of the three studied soils is ascribed to their alkaline pH and their high carbonates contents favoring the precipitation of these elements. Moreover, bivariate correlation analysis showed that sorption and retention of the studied cations was also strongly correlated with clay fraction and Fe oxides contents. All soils show high sorption irreversibility of Pb2+, Zn2+, Ni2+, Cu2+, and Co2+. The soils with highest sorption capacity show also the highest irreversibility.