Organic–inorganic bismuth (III)-based material: A lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites
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- 作者：Miaoqiang Lyu ; Jung-Ho Yun ; Molang Cai ; Yalong Jiao ; Paul V. Bernhardt…
- 关键词：methylammonium bismuth (III) iodide ; single crystal ; perovskite solar cells ; organic–inorganic hybrid material ; lead ; free
- 刊名：Nano Research
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：9
- 期：3
- 页码：692-702
- 全文大小：2,327 KB
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Jung-Ho Yun (1)
Molang Cai (2)
Yalong Jiao (2)
Paul V. Bernhardt (3)
Meng Zhang (1)
Qiong Wang (1)
Aijun Du (2)
Hongxia Wang (2)
Gang Liu (4)
Lianzhou Wang (1)
1. Nanomaterials Centre, School of Chemical Engineering and AIBN, The University of Queensland, St Lucia, Brisbane, QLD, 4072, Australia
2. School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, Brisbane, QLD, 4001, Australia
3. School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, 4072, Australia
4. Advanced Carbon Division, Institute of Metal Research Chinese Academy of Sciences (IMR CAS), 72 Wenhua Road, Shenyang, 110016, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chinese Library of Science
Chemistry
Nanotechnology - 出版者：Tsinghua University Press, co-published with Springer-Verlag GmbH
- ISSN：1998-0000
文摘
Methylammonium bismuth (III) iodide single crystals and films have been developed and investigated. We have further presented the first demonstration of using this organic–inorganic bismuth-based material to replace lead/tin-based perovskite materials in solution-processable solar cells. The organic–inorganic bismuth-based material has advantages of non-toxicity, ambient stability, and low-temperature solution-processability, which provides a promising solution to address the toxicity and stability challenges in organolead- and organotin-based perovskite solar cells. We also demonstrated that trivalent metal cation-based organic–inorganic hybrid materials can exhibit photovoltaic effect, which may inspire more research work on developing and applying organic-inorganic hybrid materials beyond divalent metal cations (Pb (II) and Sn (II)) for solar energy applications.