Research progresses of cathodic hydrogen evolution in advanced lead–acid batteries

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• 作者：Feng Wang ; Chen Hu ; Min Zhou ; Kangli Wang ; Jiali Lian ; Jie Yan…
• 关键词：Lead–carbon battery ; Ultrabattery ; Hydrogen evolution reaction ; Hydrogen inhibition
• 刊名：Chinese Science Bulletin
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：61
• 期：6
• 页码：451-458
• 全文大小：1,678 KB
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• 作者单位：Feng Wang (1)
  Chen Hu (2)
  Min Zhou (1)
  Kangli Wang (1)
  Jiali Lian (1)
  Jie Yan (1)
  Shijie Cheng (1)
  Kai Jiang (1)
  
  1. State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China
  2. China Electric Power Research Institute, Beijing, 100192, China
  
• 刊物主题：Science, general; Life Sciences, general; Physics, general; Chemistry/Food Science, general; Earth Sciences, general; Engineering, general;
• 出版者：Springer Berlin Heidelberg
• ISSN：1861-9541

文摘

Integrating high content carbon into the negative electrodes of advanced lead–acid batteries effectively eliminates the sulfation and improves the cycle life, but brings the problem of hydrogen evolution, which increases inner pressure and accelerates the water loss. In this review, the mechanism of hydrogen evolution reaction in advanced lead–acid batteries, including lead–carbon battery and ultrabattery, is briefly reviewed. The strategies on suppression hydrogen evolution via structure modifications of carbon materials and adding hydrogen evolution inhibitors are summarized as well. The review points out effective ways to inhibit hydrogen evolution and prolong the cycling life of advanced lead–acid battery, especially in high-rate partial-state-of-charge applications.