Calix Receptor Edifice; Scrupulous Turn Off Fluorescent Sensor for Fe(III), Co(II) and Cu(II)

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• 作者：Keyur D. Bhatt (1)
  Hrishikesh S. Gupte (1)
  Bharat A. Makwana (1)
  Disha J. Vyas (1)
  Debdeep Maity (2)
  Vinod K. Jain (1) drvkjain@hotmail.com
• 关键词：Fluorescent Quenching – Calix[4]resorcinarene – Ion ; binding – Dansyl chloride
• 刊名：Journal of Fluorescence
• 出版年：2012
• 出版时间：November 2012
• 年：2012
• 卷：22
• 期：6
• 页码：1493-1500
• 全文大小：515.8 KB
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• 作者单位：1. Department of Chemistry, School of Sciences, Gujarat University, Ahmedabad, 380009 India2. Analytical Science Division, Central Salt and Marine Chemicals Research Institute (Constituents of CSIR, New Delhi), G.B. Marg, Bhavnagar, 364002 India
• ISSN：1573-4994

文摘

Novel Supramolecular fluorescence receptor derived from calix-system i.e. calix[4]resorcinarene bearing dansylchloride as fluorophore was designed and synthesized. The compound was purified by column chromatography and characterized by elemental analysis, NMR and Mass spectroscopy. Tetradansylated calix[4] resorcinarene (TDCR) shows a boat conformation with C₂v symmetry. The complexation behaviour of metal cations [Ag(I), Cd(II), Co(II), Fe(III), Hg(II), Cu(II), Pb(II), Zn(II), U(VI) (1?×?10-4 M)] with tetra dansylated calix[4]resorcinarene (1?×?10-6 M) was studied by spectophotometry and spectrofluorometry. Red shift in the absorption spectra led us to conclude that there is strong complexation Fe(III), Co(II) and Cu(II) with TDCR. These metal cations also produce quenching with red shifts in the emission spectra. The maximum quenching in emission intensity was observed in the case of Fe(III) and its binding constant was also found to be significantly higher than that of Co(II) and Cu(II). Quantum yield of metal complexes of Fe(III) was found to be lower in comparison with Co(II) and Cu(II) complexes. Stern Volmer analysis indicates that the mechanism of fluorescence quenching is either purely dynamic, or purely static.