Magnetic resonance on LiCuVOB>4
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Abstract: EPR and 7Li NMR measurements were performed in the distorted inverse spinel V(LiCu)O4 down to 1.5 K. Anisotropy effects on magnetic resonance spectra due to the Jahn-Teller distortion of the oxygen octahedra surrounding the copper ions are discussed. The estimation of the spin-spin interactions deduced from the EPR-relaxation rate jH reveals a situation comparable to the prototypical one-dimensional S = 1/2 Heisenberg antiferromagnet CuGeO3. Approaching three-dimensional antiferromagnetic order ( TN , 2 K) from above, both magnetic relaxation rates, jHEPR and 7(1/T1), respectively, exhibit nearly the same critical divergence reminding to the onset of three-dimensional order in two-dimensional layered systems.

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