Metal–Organic Frameworks Based on Lanthanide Clusters
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- 关键词：Lanthanide ions ; Luminescent properties ; Magnet properties ; Metal clusters ; Metal–organic frameworks
- 刊名：Structure & Bonding
- 出版年：2015
- 出版时间：2015
- 年：2015
- 卷：163
- 期：1
- 页码：145-183
- 全文大小：2,634 KB
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Feilong Jiang (3)
Kang Zhou (3)
Mingyan Wu (3)
Maochun Hong (3)
3. State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China - 丛书名：Lanthanide Metal-Organic Frameworks
- ISBN：978-3-662-45773-3
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Inorganic Chemistry - 出版者：Springer Berlin / Heidelberg
- ISSN：1616-8550
文摘
The assembly of the metal clusters to multidimensional metal–organic frameworks remains one of the most attractive research frontiers due to its attractive architectures and excellent properties. Compared with transition metals, the cluster chemistry of lanthanide ions is less developed. The chapter mainly highlights recent research progress on the synthetic strategy, structures, and properties of metal–organic frameworks based on lanthanide clusters. Varying from di- to octatetraconta-nuclei, lanthanide clusters can act as versatile nodes to construct different fascinating topological networks by the linkage of the ligands. The cluster formations and the topologies of these compounds as well as the influence factors on them are described in detail. Potential applications in a variety of fields, especially in luminescence, magnetism, and catalysis, are shown in these materials.