4f-Clusters for Cryogenic Magnetic Cooling

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• 关键词：Cluster compounds ; Lanthanide ; Magnetic coolant ; Magnetocaloric effect ; Magnetocaloric material
• 刊名：Structure & Bonding
• 出版年：2017
• 出版时间：2017
• 年：2017
• 卷：173
• 期：1
• 页码：189-207
• 全文大小：1,230 KB
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• 作者单位：Yan-Cong Chen (3)
  Jun-Liang Liu (3)
  Ming-Liang Tong (3)
  
  3. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, 510275, China
  
• 丛书名：Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials
• ISBN：978-3-662-53303-1
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1616-8550
• 卷排序：173

文摘

Based on the magnetocaloric effect (MCE), cryogenic magnetic cooling is one of the most promising applications of molecule-based magnets. In recent years, 4f-clusters played important roles and set up several records in such area, some of which exhibit large and promising cryogenic MCE catching up the commercial coolant GGG. Here in this chapter, we focus on the structure–magnetocaloric correlations of 4f-clusters and 4f-cluster-based coordination polymers for use as cryogenic magnetic coolants. The assembly strategies are introduced and discussed on the purpose of obtaining high performance 4f-clusters for cryogenic magnetic cooling. Then, the recent development is summarized and accompanied by the discussion on representative examples. Finally, the outlooks about the future research directions in this area are made.