Synthesis and Structures of Lanthanide–Transition Metal Clusters

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• 关键词：Clusters ; Crystal structure ; Heterometallic lanthanide ; transition metal (d–f) ; Synthetic methodology
• 刊名：Structure & Bonding
• 出版年：2017
• 出版时间：2017
• 年：2017
• 卷：173
• 期：1
• 页码：51-96
• 全文大小：4,041 KB
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• 作者单位：Xiu-Ying Zheng (3)
  Xiang-Jian Kong (3)
  La-Sheng Long (3)
  
  3. State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
  
• 丛书名：Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials
• ISBN：978-3-662-53303-1
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1616-8550
• 卷排序：173

文摘

Based on the inherent contribution of the d–f electrons and the unique exchange interactions between different metal ions, heterometallic lanthanide–transition metal (d–f) clusters have received substantial attention in modern chemistry. In the past two decades, numerous lanthanide–transition metal clusters with diverse molecular structures have been obtained. Various synthetic approaches have been developed by analyzing the crystal structures and reaction conditions. In this chapter, we discussed synthetic methodology based on hard and soft acids and bases (HSAB) theory and the resulting structures. In addition, personal perspectives and outlooks regarding the future research directions of d–f molecular clusters are provided at the end of this chapter.