Lanthanide Clusters Toward Single-Molecule Magnets

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• 关键词：Lanthanide ; Magnetic relaxation ; Polynuclear 4f complexes ; Single ; molecule magnets
• 刊名：Structure & Bonding
• 出版年：2017
• 出版时间：2017
• 年：2017
• 卷：173
• 期：1
• 页码：209-314
• 全文大小：3,137 KB
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• 作者单位：Tian Han (3)
  You-Song Ding (3)
  Yan-Zhen Zheng (3)
  
  3. Frontier Institute of Science and Technology (FIST), State Key Laboratory for Mechanical Behavior of Materials and MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University, Xi’an, 710054, P. R. China
  
• 丛书名：Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials
• ISBN：978-3-662-53303-1
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1616-8550
• 卷排序：173

文摘

Single-molecule magnets (SMMs) have attracted increasing attention for their potential applications in high-density information storage and quantum computing. Thereinto, polynuclear 4f complexes are excellent candidates to create high-performance SMMs for the advantages of significant single-ion magnetic anisotropy arising from 4f ions and manipulable magnetic exchange couplings via tunable arrangement of the metal ions, which promotes the rapid development of this area in the last decade. In this chapter we present a comprehensive review focusing on cluster-based lanthanide SMMs and their correlations between the molecular structures and magnetic behaviors and further highlight some novel strategies for enhancing SMMs.