Swelling, thermal and mechanical properties of NIPAM-based terpolymeric hydrogel

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• 作者：Suman Shekhar ; M. Mukherjee ; Akhil Kumar Sen
• 关键词：NIPAM ; based terpolymer ; Swelling ; DSC ; DMA ; Diffusion ; Protein separation
• 刊名：Polymer Bulletin
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：73
• 期：1
• 页码：125-145
• 全文大小：885 KB
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• 作者单位：Suman Shekhar (1)
  M. Mukherjee (2)
  Akhil Kumar Sen (2)
  
  1. Department of Chemistry, Government Engineering College, Ramgarh, Jharkhand, India
  2. Department of Chemical Engineering and Technology, Birla Institute of Technology, Mesra, Ranchi, Jharkhand, India
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Characterization and Evaluation Materials
  Soft Matter and Complex Fluids
  Physical Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1436-2449

文摘

Thermoresponsive hydrogels based on N-isopropylacrylamide, N-tertiary butylacrylamide (NTBA) and methacrylamide (MAAm) have been prepared by free radical copolymerization in water–dioxane mixture. Fourier transform infrared spectroscopy confirmed the presence of all monomers in the hydrogel system. Scanning electron microscopy revealed that the hydrogel having higher amount of NTBA had more smooth structure compared to others. Differential scanning calorimetry results showed that the free and interfacial water decreased but bound water increased with NTBA content in the hydrogel. Dynamic mechanical analysis results revealed increased storage modulus for the hydrogel having higher content of N-tertiarybutylacrylamide. Swelling studies of the hydrogels at different temperatures showed that all samples followed Fickian type of diffusion. The diffusion coefficient increases with increase in MAAm proportion in the hydrogel. The hydrogels were used in concentrating aqueous bovine serum albumin solution. The separation efficiency of hydrogels having higher content of MAAm were found up to 80 % at 5 °C but it decreased upon raising the temperature up to 30 °C.