Bimetallic Fe–Cu Carbido Carbonyl Clusters Obtained from the Reactions of [Fe4C(CO)12{Cu(MeCN)}2] with N-Donor Ligands
详细信息 查看全文
- 作者：Iacopo Ciabatti ; Cristina Femoni ; Mohammad Hayatifar…
- 关键词：Heterometallic clusters ; Carbonyl ; Copper ; Iron ; Interstitial carbide
- 刊名：Journal of Cluster Science
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：27
- 期：2
- 页码：431-456
- 全文大小：1,229 KB
- 参考文献：1.C. Femoni, R. Della Pergola, M. C. Iapalucci, F. Kaswalder, M. Riccò, and S. Zacchini (2009). Dalton Trans. 9, 1509.CrossRef
2.R. Della Pergola, A. Sironi, L. Garlaschelli, D. Strumolo, C. Manassero, M. Manassero, S. Fedi, P. Zanello, F. Kaswalder, and Stefano Zacchini (2010). Inorg. Chim. Acta 363, 586.CrossRef
3.R. Della Pergola, A. Sironi, C. Manassero, and M. Manassero (2010). Organometallics 29, 5885.CrossRef
4.R. Della Pergola, M. Bruschi, A. Sironi, M. Manassero, C. Manassero, D. Strumolo, S. Fedi, and P. Zanello (2011). Dalton Trans. 40, 5464.CrossRef
5.R. DellaPergola, A. Sironi, M. Moret, S. Bregantin, P. R. Mussini, and M. Panigati (2013). J. Organomet. Chem. 728, 23.CrossRef
6.R. Della Pergola, A. Sironi, A. Roseher, V. Colombo, and A. Sironi (2014). Inorg. Chem. Commun. 49, 27.CrossRef
7.E. E. Chufán, S. C. Puiu, and K. D. Karlin (2007). Acc. Chem. Res. 40, 563.CrossRef
8.B. Wu, L. Tian, H. Xiang, Z. Zhang, and Y.-W. Li (2005). Catal. Lett. 102, 211.CrossRef
9.P. Braunstein, G. Clerc, and X. Morise (2003). New J. Chem. 27, 68.CrossRef
10.L. Spiccia, K. S. Murray, J. F. Young, and T. Mallah (2004). Inorg. Synth. 34, 133.
11.M. Tachikawa and E. L. Muetterties (1980). J. Am. Chem. Soc. 102, 4541.CrossRef
12.E. M. Holt, K. H. Withmire, and D. F. Shriver (1981). J. Organomet. Chem 213, 125.CrossRef
13.S. Stagni, A. Palazzi, S. Zacchini, B. Ballarin, C. Bruno, M. Marcaccio, F. Paolucci, M. Monari, M. Carano, and A. J. Bard (2006). Inorg. Chem. 45, 695.CrossRef
14.R. Della Pergola, A. Sironi, C. Manassero, and M. Manassero (2010). Organometallics 29, 5885.CrossRef
15.P. F. Jackson, B. F. G. Johnson, J. Lewis, J. N. Nicholls, M. McPartlin, and W. J. H. Nelson (1980). J. Chem. Soc. Chem. Commun. 564.
16.B. F. G. Johnson, J. Lewis, J. N. Nicholls, J. Puga, P. R. Raithby, M. J. Rosales, M. McPartlin, and W. Clegg (1983). J. Chem. Soc. Dalton Trans. 277.
17.K. Wade (1976). Adv. Inorg. Chem. Radiochem. 18, 1.
18.M. Bortoluzzi, I. Ciabatti, C. Femoni, T. Funaioli, M. Hayatifar, M. C. Iapalucci, G. Longoni, and S. Zacchini (2014). Dalton Trans. 43, 9633.CrossRef
19.I. Ciabatti, C. Femoni, M. Hayatifar, M. C. Iapalucci, and S. Zacchini (2015). Inorg. Chim. Acta 428, 203.CrossRef
20.S. Saha, L. Zhu, and B. Captain (2010). Inorg. Chem. 49, 3465.CrossRef
21.R. D. Adams, B. Captain, W. Fu, P. J. Pellecchia, and M. D. Smith (2003). Inorg. Chem. 42, 2094.CrossRef
22.D. S. Shephard, B. F. G. Johnson, A. Harrison, S. Parsons, S. P. Smidt, L. J. Yellowlees, and D. Reed (1998). J. Organomet. Chem. 563, 113.CrossRef
23.R. D. Adams, B. Captain, P. J. Pellecchia, and L. Zhu (2004). Inorg. Chem. 43, 7243.CrossRef
24.R. D. Adams, J. Tedder, and Y. O. Wong (2015). J. Organomet. Chem. 795, 2.CrossRef
25.R. Reina, O. Riba, O. Rossell, M. Seco, P. Gomez-Sal, A. Martin, D. de Montauzon, and A. Mari (1998). Organometallics 17, 4127.CrossRef
26.R. D. Adams, B. Captain, W. Fu, P. J. Pellecchia, and M. D. Smidt (2002). Angew. Chem. Int. Ed. 41, 1951.CrossRef
27.D. J. Darensbourg, E. M. Longridge, E. V. Atnip, and J. H. Reibenspies (1992). Inorg. Chem. 31, 3951.CrossRef
28.Z. Huang and J. F. Hartwig (2012). Angew. Chem. Int. Ed. 51, 1028.CrossRef
29.P. C. Healy, L. M. Engelhardt, V. A. Patrick, and A. H. White (1985). J. Chem. Soc. Dalton Trans. 12, 2541.CrossRef
30.C. Dey and R. Banerjee (2013). ChemPhysChem 14, 1009.CrossRef
31.S. K. Hoffmann, P. J. Corvan, P. Singh, C. N. Sethulekshmi, R. M. Metzger, and W. E. Hatfield (1983). J. Am. Chem. Soc. 105, 4608.CrossRef
32.K. Latham, K. F. White, K. B. Szpakolski, C. J. Rix, and J. M. White (2009). Inorg. Chim. Acta 362, 1872.CrossRef
33.J. W. Tye, Z. Weng, R. Giri, and J. F. Hartwig (2010). Angew. Chem. Int. Ed. 49, 2185.CrossRef
34.S.-L. Zheng, M. Gembicky, M. Messerschmidt, P. M. Dominiak, and P. Coppens (2006). Inorg. Chem. 45, 9281.CrossRef
35.R. D. Adams, R. Layland, and K. McBride (1996). Organometallics 15, 5425.CrossRef
36.B. F. G. Johnson, D. A. Kaner, J. Lewis, P. R. Raithby, and M. J. Rosales (1982). J. Organomet. Chem. 231, C59.CrossRef
37.J. A. Hrijac, P. N. Swepston, and D. F. Shriver (1985). Organometallics 4, 158.CrossRef
38.M. Tachikawa, A. C. Sievert, E. L. Muetterties, M. R. Thompson, C. S. Day, and V. W. Day (1980). J. Am. Chem. Soc. 102, 1725.CrossRef
39.S. Saha, L. Zhu, and B. Captain (2010). Inorg. Chem. 49, 3465.CrossRef
40.R. Reina, O. Riba, O. Rossell, M. Seco, P. Gomez-Sal, and A. Martin (1997). Organometallics 16, 5113.CrossRef
41.O. Rossell, M. Seco, G. Segales, S. Alvarez, M. A. Pellinghelli, A. Tiripicchio, and D. de Montauzon (1997). Organometallics 16, 236.CrossRef
42.R. D. Adams, B. Captain, and W. Fu (2001). J. Clust. Sci. 12, 303.CrossRef
43.J. Camats, R. Reina, O. Riba, O. Rossell, M. Seco, P. Gomez-Sal, A. Martin, and D. de Montauzon (2000). Organometallics 19, 3316.CrossRef
44.O. Rossell, M. Seco, G. Segales, B. F. G. Johnson, P. J. Dyson, and S. L. Ingham (1996). Organometallics 15, 884.CrossRef
45.E. Keller SCHAKAL99 (University of Freiburg, Germany, 1999).
46.G. M. Sheldrick SADABS, Program for Empirical Absorption Correction (University of Göttingen, Göttingen, 1996).
47.G. M. Sheldrick SHELX97, Program for Crystal Structure Determination (University of Göttingen, Göttingen, 1997). - 作者单位：Iacopo Ciabatti (1)
Cristina Femoni (1)
Mohammad Hayatifar (1)
Maria Carmela Iapalucci (1)
Irene Maggiore (1)
Stefano Stagni (1)
Stefano Zacchini (1)
1. Dipartimento di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale Risorgimento 4, 40136, Bologna, Italy - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Catalysis
Inorganic Chemistry
Physical Chemistry - 出版者：Springer Netherlands
- ISSN：1572-8862
文摘
The reaction of [Fe4C(CO)12{Cu(MeCN)}2] (1) with 3 equivalents of L–L (phen or Me2phen) affords [Cu(L–L)2][Fe4C(CO)12{Cu(L–L)}] (L–L = phen, 2; Me2phen, 3) in good yields. These are protonated by strong acids resulting in [HFe4C(CO)12{Cu(L–L)}] (L–L = phen, 4; Me2phen, 5). The reaction may be reversed with bases, resulting in the quaternary ammonium salts [NR4][Fe4C(CO)12{Cu(phen)}] (6). 4 and 5 react with a slight excess of L–L resulting in the elimination of copper in the form of [Cu(L–L)2]+ and formation of the previously reported [HFe4C(CO)12]− homometallic cluster. Conversely, the reaction of 1 with a monodentate N-ligand such as quinoline, even if used in large excess, results in the substitution product [Fe4C(CO)12{Cu(quinoline)}2] (8), which is then transformed into [Cu(Me2phen)2] [Fe4C(CO)12{Cu(quinoline)}] (9) after reaction with Me2phen. By using the anionic cluster [Fe5C(CO)14{Cu(MeCN)}]− instead of the neutral 1, only substitution has been observed by using both phen and quinoline, resulting in [Fe5C(CO)14{Cu(phen)}]− (10) and [Fe5C(CO)14{Cu(quinoline)}]− (11), respectively. Finally, the reaction of 1 with [Ru(tpy)(bpy)(N4C-C6H4-CN)]Cl affords crystals of [Fe4C(CO)12Cu2Cl{Ru(tpy)(bpy)(N4C-C6H4-CN)}] (12). All compounds 2-12 have been characterized by a combination of spectroscopic (IR, NMR) and crystallographic methods. All these clusters may be viewed as composed by a butterfly [Fe4C(CO)12]2− core bonded to Cu(I) fragments and/or H+ ions.