Ni0.1Co0.9Fe2O4-based electrochemical sensor for the detection of paracetamol
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  • 作者:Anitha Kumary Vidyadharan ; Divya Jayan…
  • 关键词:Paracetamol ; Cyclic voltammetry ; Chronoamperometry ; Dopamine
  • 刊名:Journal of Solid State Electrochemistry
  • 出版年:2014
  • 出版时间:September 2014
  • 年:2014
  • 卷:18
  • 期:9
  • 页码:2513-2519
  • 全文大小:794 KB
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  • 作者单位:Anitha Kumary Vidyadharan (1)
    Divya Jayan (1)
    T. E. Mary Nancy (1)

    1. Department of Chemistry, Sree Narayana College for Women, Kollam, Kerala, 691001, India
  • ISSN:1433-0768
文摘
A novel electrochemical sensor based on nickel-doped cobalt ferrite nanoparticles (Ni0.1Co0.9Fe2O4)-modified glassy carbon electrode (NCF/GCE) was presented for the sensitive detection of paracetamol. Experimental conditions such as pH, applied potentials and concentration were investigated using cyclic voltammetric and chronoamperometric techniques. The modified electrode exhibited excellent catalytic response towards the oxidation of paracetamol with good reproducibility. The overpotential for oxidation of paracetamol is decreased, and the current response enhanced significantly on the modified electrode in comparison with that of bare electrode. Linear calibration curve is obtained over the range 2?μM to 8,000?μM having a detection limit of 11?nM. The modified electrode facilitated the simultaneous detection of paracetamol, ascorbic acid, and dopamine with good reproducibility.

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