Steam reforming of ethylene glycol over Ni-based catalysts: the effect of K

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• 作者：Dong Hyuck Choi ; Jung Eun Park ; Dong Ha Kim…
• 关键词：Ethylene glycol ; Steam reforming ; Nickel ; Aluminum oxide ; Potassium ; Promoter
• 刊名：Research on Chemical Intermediates
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：42
• 期：1
• 页码：223-235
• 全文大小：1,425 KB
• 参考文献：1.C. Liu, H. Wang, A.M. Karim, J. Suna, Y. Wang, Chem. Soc. Rev. 43, 7594 (2014)CrossRef
  2.C.-H. Zhou, X. Xia, C.-X. Lin, D.-S. Tonga, J. Beltramini, Chem. Soc. Rev. 40, 5588 (2011)CrossRef
  3.N. Ji, T. Zhang, M. Zheng, A. Wang, H. Wang, X. Wang, J.G. Chen, Angew. Chem. Int. Ed. 47, 8510 (2008)CrossRef
  4.R.R. Davda, J.W. Shabaker, G.W. Huber, R.D. Cortright, J.A. Dumesic, Appl. Catal. B 43, 13 (2003)CrossRef
  5.J.W. Shabaker, R.R. Davda, G.W. Huber, R.D. Cortright, J.A. Dumesic, J. Catal. 215, 344 (2003)CrossRef
  6.G.W. Huber, J.W. Shabaker, S.T. Evans, J.A. Dumesic, Appl. Catal. B 62, 226 (2006)CrossRef
  7.N. Wang, N. Perret, A. Foster, Int. J. Hydrogen Energy 36, 5932 (2011)CrossRef
  8.D.J.M. Vlieger, A.G. Chakinala, L. Lefferts, S.R.A. Kersten, K. Seshan, D.W.F. Brilman, Appl. Catal. B 111–112, 536 (2012)CrossRef
  9.Y.S. Jung, W.L. Yoon, Y.W. Rhee, Y.S. Seo, Int. J. Hydrogen Energy 37, 9340 (2012)CrossRef
  10.F. Marino, M. Boveri, G. Baronetti, M. Laborde, Int. J. Hydrogen Energy 26, 665 (2001)CrossRef
  11.A.C. Basagiannis, X.E. Verykios, Appl. Catal. A 308, 182 (2006)CrossRef
  12.P. Biswas, D. Kunzru, Int. J. Hydrogen Energy 32, 969 (2007)CrossRef
  13.L. Zhang, J. Liu, W. Li, C. Guo, J. Zhang, J. Nat. Gas Chem. 18, 55 (2009)CrossRef
  14.A. Haryanto, S. Fernando, N. Murali, S. Adhikari, Energy Fuels 19, 2098 (2005)CrossRef
  15.G. Garbarino, A. Lagazzo, P. Riani, G. Busca, Appl. Catal. B 129, 460 (2013)CrossRef
  16.V. Nichele, M. Signoretto, F. Menegazzo, A. Gallo, V.D. Santo, G. Cruciani, G. Cerrato, Appl. Catal. B 111–112, 225 (2012)CrossRef
  17.N. Goyal, K.K. Pant, R. Gupta, Int. J. Hydrogen Energy 38, 921 (2013)CrossRef
  18.P.R. Piscina, N. Homs, Chem. Soc. Rev. 37, 2459 (2008)CrossRef
  19.J.H. Kim, D.J. Suh, T.J. Park, K.L. Kim, Appl. Catal. A 197, 191 (2000)CrossRef
  20.G. Li, L. Hu, J. Hill, Appl. Catal. A 301, 16 (2006)CrossRef
  21.I.E. Achouri, N. Abatzoglou, C. Fauteux-Lefebvre, N. Braidy, Catal. Today 207, 13 (2013)CrossRef
  22.H.H. Ibrahim, P. Kumar, R. Idem, Energy Fuels 21, 570 (2007)CrossRef
  23.Y.S. Jung, W.L. Yoon, Y.S. Seo, Y.W. Rhee, Catal. Commun. 26, 103 (2012)CrossRef
  24.D.H. Choi, J.E. Park, E.D. Park, Korean Chem. Eng. Res. 53(3), 372 (2015)CrossRef
  25.S.K.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem. 57, 603 (1985)CrossRef
  26.C.S. Chen, J.H. Lin, J.H. You, K.H. Yang, J. Phys. Chem. A 114, 3773 (2010)CrossRef
  27.L.V. Mattos, G. Jacobs, B.H. Davis, F.B. Noronha, Chem. Rev. 112, 4094 (2012)CrossRef
  28. L. Zhao, Y. Wei, Y. Huang, Y. Liu, Catal. Today. (2015). doi:10.​1016/​j.​cattod.​2015.​04.​013
  29.T. Borowiecki, A. Denis, M. Rawski, A. Golebiowski, K. Stolecki, J. Dmytrzyk, A. Kotarba, Appl. Surf. Sci. 300, 191 (2014)CrossRef
  
• 作者单位：Dong Hyuck Choi (1)
  Jung Eun Park (1)
  Dong Ha Kim (1)
  Eun Duck Park (1)
  
  1. Department of Chemical Engineering and Department of Energy Systems Research, Ajou University, 206, World cup-ro, Yeongtong-Gu, Suwon, 443-749, Republic of Korea
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

The effect of K on the activities of Ni/Al₂O₃ catalysts in steam reforming of ethylene glycol was investigated. Ni/Al₂O₃ catalysts were prepared by incipient wetness impregnation and co-precipitation methods. The addition of K was achieved using an incipient wetness impregnation method. The prepared catalysts were characterized by N₂ physisorption, inductively coupled plasma-atomic emission spectroscopy, X-ray diffraction, temperature-programmed reduction, and scanning electron microscopy. Irrespective of the preparation method, the promotional effect of K was observed and the optimum K content (~5 wt%) was verified for K-promoted Ni/Al₂O₃ catalysts. The addition of K to the Ni–Al₂O₃ catalyst prepared by co-precipitation led to higher catalytic activity than addition of K to the Ni/Al₂O₃ catalyst prepared by incipient wetness impregnation. Keywords Ethylene glycol Steam reforming Nickel Aluminum oxide Potassium Promoter