The effects of Tb3+ doping concentration on luminescence properties and crystal structure of BaF2 phosphor
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  • 作者:ZHENXING DU ; QUANSHENG LIU ; TIANJIANG HOU ; YUE SONG…
  • 关键词:BaF2 phosphor ; crystal structure ; luminescence properties ; X ; ray diffraction ; concentration quenching.
  • 刊名:Bulletin of Materials Science
  • 出版年:2015
  • 出版时间:June 2015
  • 年:2015
  • 卷:38
  • 期:3
  • 页码:805-809
  • 全文大小:449 KB
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  • 作者单位:ZHENXING DU (1)
    QUANSHENG LIU (1)
    TIANJIANG HOU (1)
    YUE SONG (1)
    XIYAN ZHANG (1)
    YANYU CUI (1)

    1. Engineering Research Center of Optoelectronic Functional Materials of the Ministry of Education, Changchun University of Science and Technology, Changchun, 130022, PR China
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Materials Science
    Engineering, general
  • 出版者:Springer India
  • ISSN:0973-7669
文摘
This paper is aimed at explaining the effects of Tb3+ concentration on structure and luminescence properties and clarifying the concentration quenching mechanism of Tb3+. The lattice of BaF2 decreases with the increase of Tb3+ ions concentration. The emission spectrum of BaF2:Tb3+ consists of blue emission band and green emission band and corresponds to the transition of 5D3?sup>7F J (J = 0, 1, 2, 4, 5, 6) and 5D4 ?7F J (J = 2, 3, 4, 5, 6) of Tb3+. The optimum concentration of Tb3+ is 4 mol%, and the concentration quenching mechanism of Tb3+ can be interpreted by the dipole–quadrupole (d–q) interaction.

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