Synthesis and catalytic activity to Li/SOCl2 battery of asymmetric and symmetric binuclear metal phthalocyanines

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• 作者：Q. Q. Jiang ; S. W. Li ; F. Yang ; N. Zhao ; F. X. Zhang…
• 关键词：binuclear phthalocyanines ; Li/SOCl2 battery ; catalytic activity ; capacity ; energy
• 刊名：Russian Journal of Electrochemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：52
• 期：2
• 页码：136-142
• 全文大小：630 KB
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• 作者单位：Q. Q. Jiang (1)
  S. W. Li (1)
  F. Yang (1)
  N. Zhao (1)
  F. X. Zhang (1)
  J. S. Zhao (1)
  S. C. Zhang (2)
  J. L. Wang (3)
  
  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science, Northwest University, Xi’an, Shaanxi, 710069, PR China
  2. School of Material Science and Engineering, Beihang University, XueYuan Road No.37, HaiDian District, Beijing, 100191, PR China
  3. Composites Research Institute, Weinan Normal University, Weinan, 714000, PR China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3342

文摘

In our present work, the asymmetric and symmetric binuclear metal phthalocyanines (M₂(PcTN)₂ and M₂(PcTN)₂S), battery catalysts, were synthesized through microwave reaction and characterized by EA, IR and UV-vis spectroscopy. Their catalytic activity in the Li/SOCl₂ battery was evaluated by adding right amount catalysts into the electrolyte. The results indicated that the capacity of the catalyzed battery increased by 6.74–67.26% and 13.41–84.36%, and the energy increased by 9.29–65.72% and 14.77–88.15% respectively, compared with the battery without phthalocyanines.