Nucleophilic substitution in 4-bromo-5-nitrophthalonitrile: XIV. Synthesis and properties of 4,5-bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile and phthalocyanines therefrom
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- 作者：S. A. Znoiko ; M. A. Serova ; A. A. Uspenskaya…
- 关键词：4 ; bromo ; 5 ; nitrophthalonitrile ; nucleophilic substitution ; metal phthalocyanines ; electronic absorption spectra
- 刊名：Russian Journal of General Chemistry
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：86
- 期：11
- 页码：2501-2507
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry/Food Science, general;
- 出版者：Pleiades Publishing
- ISSN：1608-3350
- 卷排序：86
文摘
4,5-Bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile was prepared by the nucleophilic substitution of the nitro group and bromine in 4-bromo-5-nitrophathalonitrile. The product was used to synthesize the corresponding octasubstituted phthalocyanine, as well as its magnesium, copper, zinc, cobalt, and nickel complexes. The spectral properties of the synthesized phthalocyanines were studied.