Direct Synthesis of Co-doped Graphene on Dielectric Substrates Using Solid Carbon Sources

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• 作者：Qi Wang ; Pingping Zhang ; Qiqi Zhuo ; Xiaoxin Lv ; Jiwei Wang ; Xuhui Sun
• 关键词：Graphene ; Solid carbon sources ; Transfer ; free ; Doping and co ; doping
• 刊名：Nano-Micro Letters
• 出版年：2015
• 出版时间：October 2015
• 年：2015
• 卷：7
• 期：4
• 页码：368-373
• 全文大小：1,903 KB
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• 作者单位：Qi Wang (1)
  Pingping Zhang (1)
  Qiqi Zhuo (1)
  Xiaoxin Lv (1)
  Jiwei Wang (1)
  Xuhui Sun (1)
  
  1. Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano & Soft Materials, Soochow University, Suzhou, 215123, Jiangsu, People鈥檚 Republic of China
  
• 刊物类别：Nanotechnology and Microengineering; Nanotechnology; Nanoscale Science and Technology;
• 刊物主题：Nanotechnology and Microengineering; Nanotechnology; Nanoscale Science and Technology;
• 出版者：Springer Berlin Heidelberg
• ISSN：2150-5551

文摘

Direct synthesis of high-quality doped graphene on dielectric substrates without transfer is highly desired for simplified device processing in electronic applications. However, graphene synthesis directly on substrates suitable for device applications, though highly demanded, remains unattainable and challenging. Here, a simple and transfer-free synthesis of high-quality doped graphene on the dielectric substrate has been developed using a thin Cu layer as the top catalyst and polycyclic aromatic hydrocarbons as both carbon precursors and doping sources. N-doped and N, F-co-doped graphene have been achieved using TPB and F₁₆CuPc as solid carbon sources, respectively. The growth conditions were systematically optimized and the as-grown doped graphene were well characterized. The growth strategy provides a controllable transfer-free route for high-quality doped graphene synthesis, which will facilitate the practical applications of graphene. Keywords Graphene Solid carbon sources Transfer-free Doping and co-doping