Effect of the Li2O: ZnO ratio on the kinetics of cathode luminescence and optical properties of phosphate glass activated by Dy3+

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• 作者：E. F. Polisadova (1)
  H. A. Othman (2)
  V. M. Lisitsyn (1)
  
• 关键词：luminescence ; phosphate glass ; decay kinetics ; dysprosium ion ; excitation energy transfer ; phosphate chain length ; oxygen packing density
• 刊名：Glass Physics and Chemistry
• 出版年：2014
• 出版时间：March 2014
• 年：2014
• 卷：40
• 期：2
• 页码：138-143
• 全文大小：343 KB
• 参考文献：1. Alekseev, N.E., Gapontsev, V.P., Zhabotinskii, M.E., Kravchenko, V.B., and Rudnitskii, Yu.P., / Lazernye fosfatnye stekla (Laser Phosphate Glasses), Zhabotinskii, M.E., Ed., Moscow: Nauka, 1980.
  2. Gavrilov, D.S., Dmitrov, D.A., Kakshin, A.G., Kapustin, I.A., and Loboda, E.A., 30 TW picosecond laser system “Sokol-P,-in / XI Zababakhinskie nauchnye chteniya (Proceedings of the XI Zababakhin Scientific Readings, Snezhinsk, Chelyabinsk oblast, Russia, April 16-0, 2012), Snezhinsk, 2012.
  3. Myers, J., Wu, R., Chen, T., Myers, M., Hardy, C.R., and Driver, J.K., Phosphate glass fiber laser materials and architectures, in / Proceedings of the 16th Annual Solid State and Diode Laser Technology Review (SSDTR-2033), Albuquerque, New Mexico, United States, May 20-2, 2003, Albuquerque: Directed Energy Professional Society, 2003.
  4. Zhengqing Pan, Haiwen Cai, Li Meng, Jianxin Geng, Qing Ye, Zujie Fang, and Ronghui Qu, Single-frequency phosphate glass fiber laser with 100-mW output power at 1535 nm and its polarization characteristics, / Chin. Opt. Lett., 2010, vol. 8, no. 1, pp. 52-4. external" href="http://dx.doi.org/10.3788/COL20100801.0052" target="_blank" title="It opens in new window">CrossRef
  5. Chaofeng Zhu, Yunxia Yang, Xiaoluan Liang, Shuanglong Yuan, and Guorong Chen, Rare-earth ions doped full-color luminescence glasses for white LED, / J. Lumin., 2007, vol. 126, no. 2, pp. 707-10. external" href="http://dx.doi.org/10.1016/j.jlumin.2006.10.028" target="_blank" title="It opens in new window">CrossRef
  6. Shimin Liu, Gaoling Zhao, Hao Ying, Jianxun Wang, and Gaorong Han, Eu/Dy ions co-doped white light luminescence zinc-aluminoborosilicate glasses for white LED, / Opt. Mater., 2008, vol. 31, no. 1, pp. 47-0. external" href="http://dx.doi.org/10.1016/j.optmat.2008.01.007" target="_blank" title="It opens in new window">CrossRef
  7. Babu, S.S., Babu, P., Jayasankar, C.K., Sievers, W., Tr?ster, Th., and Wortmann, G., Optical absorption and photoluminescence studies of Eu³⁺-doped phosphate and fluorophosphate glasses, / J. Lumin., 2007, vol. 126, pp. 109-20. external" href="http://dx.doi.org/10.1016/j.jlumin.2006.05.010" target="_blank" title="It opens in new window">CrossRef
  8. Karapetyan, K.G., Kuznetsov, A.R., and Nikitina, C.I., Spectral luminescence investigations of fluorophosphate glasses activated by neodymium, / Fiz. Khim. Stekla, 1990, vol. 16, no. 5, pp. 774-76.
  9. Grigor’ev, A.I., Tsetlin, V.V., and Pavlushkina, T.K., Semiconductor photo-transducer of solar energy for spacecrafts, RF Patent 2144718 H01L31/04 (January 20, 2000).
  10. Mironov, A.M., Influence of the composition and structure of fluorophosphate and niobium phosphate glasses on the spatial distribution of rare-earth ions in the vitreous matrix, / Extended Abstract of Candidate’s Dissertation in Chemistry, St. Petersburg, 2005.
  11. Xiaoluan Liang, Zhongwen Xing, Yunxia Yang, Shufen Wang, and Guorong Chen, Luminescence properties of Eu²⁺/Mn²⁺ co-doped borophosphate glasses, / J. Am. Ceram. Soc., 2011, vol. 94, no. 3, pp. 849-53. external" href="http://dx.doi.org/10.1111/j.1551-2916.2010.04189.x" target="_blank" title="It opens in new window">CrossRef
  12. Weina Xu, Qingwu Peng, Junhui Dong, Yu Gao, Xiaoluan Liang, Shufen Wang, and Guorong Chen, Photoluminescence properties and energy transfer of Dy³⁺-Eu³⁺ co-doped phosphate glasses, / J. Am. Ceram. Soc., 2010, vol. 93, no. 10, pp. 3064-067. external" href="http://dx.doi.org/10.1111/j.1551-2916.2010.04024.x" target="_blank" title="It opens in new window">CrossRef
  13. Korepanov, V.I., Lisitsyn, V.M., and Oleshko, V.I., High-current nanosecond electron beams for probing the parameters of solids, / Russ. Phys. J., 2000, vol. 43, no. 3, pp. 185-92. external" href="http://dx.doi.org/10.1007/BF02509607" target="_blank" title="It opens in new window">CrossRef
  14. Sales, B.C., Otaigbe, J.U., Beall, G.H., Boatner, L.A., and Ramey, J.O., Structure of zinc polyphosphate glasses, / J. Non-Cryst. Solids, 1998, vol. 226, no. 3, pp. 287-93. external" href="http://dx.doi.org/10.1016/S0022-3093(98)00415-3" target="_blank" title="It opens in new window">CrossRef
  15. Munia Ganguli and Rao, K.J., Studies of ternary Li₂SO₄-Li₂O-P₂O₅ glasses, / J. Non-Cryst. Solids, 1999, vol. 243, nos. 2-, pp. 251-67. external" href="http://dx.doi.org/10.1016/S0022-3093(98)00832-1" target="_blank" title="It opens in new window">CrossRef
  16. Inokuti, M. and Hirayama, F.J., Influence of energy transfer by the exchange mechanism on donor luminescence, / Chem. Phys., 1965, vol. 43, p. 1978. external" href="http://dx.doi.org/10.1063/1.1697063" target="_blank" title="It opens in new window">CrossRef
  17. Basiev, T.T., Voron’ko, Yu.K., Mamedov, T.G., Osiko, V.V., and Shcherbakov, I.A., Relaxation processes of excitation of metastable levels of rare-earth ions in crystals, in / Spektroskopiya kristallov (Spectroscopy of Crystals), Moscow: Nauka, 1975, p. 155.
  18. Lisitsyn, V.M., Polisadova, E.F., and Othman, H.A., Spectroscopic properties of Dy³⁺-doped phosphate glass, in / Modern Technique and Technologies (MTT-2009): Proceedings of the 15th International Scientific and Practical Conference of Students, Post-Graduates, and Young Scientists, Tomsk, Russia, May 4-, 2009, Tomsk: TPU Press, 2009, pp. 94-6.
  19. Venkatramu, V., Babu, P., and Jayasankar, C.K., Fluorescence properties of Eu³⁺ ions doped borate and fluoroborate glasses containing lithium, zinc, and lead, / Spectrochim. Acta, Part A, 2006, vol. 63, pp. 276-81. external" href="http://dx.doi.org/10.1016/j.saa.2005.05.010" target="_blank" title="It opens in new window">CrossRef
  20. Gapontsev, V.P., Gromov, A.K., Izyneev, A.A., Kravchenko, V.B., Paramonova, N.A., and Rudnitskii, Yu.P., Spectral-luminescence properties of phosphate, borophosphate, and fluorophosphate glasses activated by erbium, in / Spektroskopiya kristallov (Spectroscopy of Crystals), Moscow: Nauka, 1975, p. 337.
  
• 作者单位：E. F. Polisadova (1)
  H. A. Othman (2)
  V. M. Lisitsyn (1)
  
  1. National Research University Tomsk Polytechnical Unviverstity (TPU), pr. Lenina 30, Tomsk, 634050, Russia
  2. Minoufiya University, Shibin El Kom, Egypt
  
• ISSN：1608-313X

文摘

Synthesis of glass system with the composition (mol. %) 50P2O5-(50 - x)Li2O - xZnO + 5 wt % Dy2O3 has been described. IR absorption spectra and the kinetics of cathodeluminescence at x ranges from 0 up to 50 has been investigated. With the replacement of Li by Zn, a decrease of the oxygen ions-packing density and the average phosphate chain length could be observed. The increase of the ZnO quantity in the glass composition results in the luminescence decay time decreased from 240 to 50 μs in the 481 and 573 nm bands: here, the branching coefficient for the 4F9/2 energy level undergoes changes. The luminescence kinetics are well described by the Inokyti-Hiroyama model for the dipole-dipole mechanism.