Microwave-Assisted Free Radical Polymerizations

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• 关键词：Conventional heating ; Free radical polymerizations ; Heterogeneous polymerization ; Homogeneous polymerization ; Microwave irradiation
• 刊名：Advances in Polymer Science
• 出版年：2016
• 出版时间：2016
• 年：2016
• 卷：274
• 期：1
• 页码：87-129
• 全文大小：961 KB
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• 作者单位：Liangjing Fang (22) (23)
  Guang Han (22) (23)
  Huiqi Zhang (22) (23)
  
  22. Key Laboratory of Functional Polymer Materials, Ministry of Education, Nankai University, Tianjin, 300071, P. R. China
  23. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
  
• 丛书名：Microwave-assisted Polymer Synthesis
• ISBN：978-3-319-42241-1
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1436-5030
• 卷排序：274

文摘

Microwave irradiation has drawn rapidly increasing interest in the field of polymer science as an alternative heating method for polymer syntheses and modification, mainly because of its obvious advantages over conventional heating methods as the heating is non-contact, instantaneous and rapid, and highly specific. Many different kinds of microwave-assisted polymerizations have been developed in the past three decades, such as various microwave-assisted free radical polymerizations, step-growth polymerizations, and ring-opening polymerizations, which normally showed dramatically accelerated polymerization rates in comparison with those performed under conventional heating conditions. In this chapter, we provide a detailed overview of microwave-assisted conventional free radical polymerizations and their applications for the rapid and efficient preparation of a diverse range of polymer materials. The progress of both homogeneous (i.e., bulk polymerization and solution polymerization) and heterogeneous (including suspension polymerization, emulsion polymerization, dispersion polymerization, precipitation polymerization, and some other heterogeneous polymerizations) microwave-assisted conventional free radical polymerizations is presented. In addition, some important issues and perspectives in this research area are also discussed.