Electrochemical performance of aluminum niobium oxide as anode for lithium-ion batteries
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- 作者：Qi Wang ; Fu-Chi Wang ; Xing-Wang Cheng
- 关键词：Aluminum niobium oxide ; Electrochemical performance ; Anode ; Lithium ; ion batteries
- 刊名：Rare Metals
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：35
- 期：3
- 页码：256-261
- 全文大小：1,259 KB
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Fu-Chi Wang (1)
Xing-Wang Cheng (1)
1. School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Metallic Materials
Chinese Library of Science - 出版者：Journal Publishing Center of University of Science and Technology Beijing, in co-publication with Sp
- ISSN：1867-7185
文摘
AlNbO4, as lithium-ion batteries (LIBs) anode, has a high theoretical capacity of 291.5 mAh·g−1. Here, AlNbO4 anode materials were synthesized through a simple solid-state method. The structure, morphology and electrochemical performances of AlNbO4 anode were systematically investigated. The results show that AlNbO4 is monoclinic with C2/m space group. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations reveal the AlNbO4 particles with the size of 100 nm–2 μm. As a lithium-ion batteries anode, AlNbO4 delivers a high reversible capacity and good rate capability. The discharge capacity is as high as 151.0 mAh·g−1 after 50 charge and discharge cycles at 0.1C corresponding to capacity retention of 90.7 %. When the current density increases to 5.0C, AlNbO4 anode displays reversible discharge capacity of 73.6 mAh·g−1 at the 50th cycle.