Immobilization of multifunctional silsesquioxane cage on precipitated silica supports
详细信息 查看全文
- 作者：K. Szwarc-Rzepka (1)
B. Marciniec (2)
T. Jesionowski (1) - 关键词：Multifunctional silsesquioxane cage ; Silica ; Immobilization ; Functionalization ; Chemisorption
- 刊名：Adsorption
- 出版年：2013
- 出版时间：4 - April 2013
- 年：2013
- 卷：19
- 期：2
- 页码：483-494
- 全文大小：1123KB
- 参考文献：1. Ambrozewicz, D., Mariniec, B., Jesionowski, T.: New POSS/magnesium silicate nano-hybrids obtained by chemical or mechanical methods. Chem. Eng. J. 210, 229-36 (2012) CrossRef
2. Baney, R.H., Itoh, M., Sakakibara, A., Suzuki, T.: Silsesquioxanes. Chem. Rev. 95, 1409-430 (1995) CrossRef
3. Berendsen, G.E., de Golan, L.: Preparation and chromatographic properties of some chemically bonded phases for reversed-phase liquid chromatography. J. Liq. Chromatogr. 1, 561-86 (1978) CrossRef
4. Bergna, E.H., Roberts, O.W.: Colloidal Silica. Fundamentals and Applications. CRC Press, Boca Raton (2006)
5. Blanco, I., Abate, L., Bottino, F.A., Bottino, P., Chiacchio, M.A.: Thermal degradation of differently substituted cyclopentyl Polyhedral Oligomeric Silsesquioxane (CP-POSS) nanoparticles. J. Therm. Anal. Calorim. 107, 1083-091 (2012) CrossRef
6. Bula, K., Jesionowski, T., Krysztafkiewicz, A., Janik, J.: The effect of filler surface modification and processing conditions on distribution behaviour of silica nanofillers in polyesters. Colloid Polym. Sci. 285, 1267-273 (2007) CrossRef
7. Carniato, F., Bisio, Ch., Boccaleri, E., Guidotti, M., Gavrilova, E., Marchese, L.: Titanosilsesquioxane anchored on mesoporous silicas: a novel approach for the preparation of heterogeneous catalysts for selective oxidations. Chem. Eur. J. 14, 8098-101 (2008) CrossRef
8. Chiang, C.L., Ma, C.C.M., Wu, D.L., Kuan, H.C.: Preparation, characterization, and properties of novolac-type phenolic/SiO2 hybrid organic–inorganic nanocomposite materials by sol–gel method. J Polym Sci Polym Chem 41, 905-13 (2003) CrossRef
9. Chiu, Y.C., Riang, L., Chou, I.-C., Ma, C.-C.M., Chiang, C.-L., Yang, C.-C.: The POSS side chain epoxy nanocomposite: synthesis and thermal properties. J. Polym. Sci. B 48, 643-52 (2010) CrossRef
10. Choi, J., Harcup, J., Yee, A.F., Zhu, Q., Laine, R.M.: Organic/inorganic hybrid composites from cubic silsesquioxanes. J. Am. Chem. Soc. 123, 11420-1430 (2001) CrossRef
11. Choma, J., Zawi?lak, A., Górka, J.: Synthesis and adsorption properties of colloid-imprinted mesoporous carbons using poly(vinylidene chloride- / co-vinyl chloride) as a carbon precursor. Adsorption 15, 167-71 (2009) CrossRef
12. Filho, N.L.D., de Aquino, H.A., Pires, G., Caetano, L.: Relationship between the dielectric and mechanical properties and the ratio of epoxy resin to hardener of the hybrid thermosetting polymers. J. Braz. Chem. Soc. 17, 533-41 (2006) CrossRef
13. Fong, H., Dickens, S.H., Flaim, G.M.: Evaluation of dental restorative composites containing polyhedral oligomeric silsesquioxane methacrylate. Dent. Mater. 21, 520-29 (2005) CrossRef
14. Georgakilas, V., Bourlinos, A.B., Zboril, R., Trapalis, C.: Synthesis, characterization and aspects of superhydrophobic functionalized carbon nanotubes. Chem. Mater. 20, 2884-886 (2008) CrossRef
15. Goffin, A.-L., Duquesne, E., Moins, S., Alexandre, M., Dubois, Ph.: New organic–inorganic nanohybrids via ring opening polymerization of (di)lactones initiated by functionalized polyhedral oligomeric silsesquioxane. Eur. Polym. J. 43, 4103-113 (2007) CrossRef
16. Grudzien, R.M., Grabicka, B.E., Jaroniec, M.: Effect of organosilane/polymer ratio on adsorption properties of periodic mesoporous ethane–silica. Colloids Surf. A 300, 235-44 (2007) CrossRef
17. Jesionowski, T.: Effect of surfactants on the size and morphology of the silica particles prepared by an emulsion technique. J. Mater. Sci. 37, 5275-281 (2002) CrossRef
18. Jesionowski, T.: Preparation of spherical silica in emulsion systems using the co-precipitation technique. Mater. Chem. Phys. 113, 839-49 (2009) CrossRef
19. Jesionowski, T., Krysztafkiewicz, A., Pokora, M., Waszak, D., Tylus, W.: Physicochemical and morphological properties of hydrated silicas precipitated following alkoxysilane surface modification. Appl. Surf. Sci. 205, 212-24 (2003) CrossRef
20. Jesionowski, T., Ciesielczyk, F., Krysztafkiewicz, A.: Influence of selected alkoxysilanes on dispersive properties and surface chemistry of spherical silica precipitated in emulsion media. Mater. Chem. Phys. 119, 65-4 (2010) CrossRef
21. Jeziorska, R., Swierz-Motysia, B., Szadkowska, A., Marciniec, B., Maciejewski, H., Dutkiewicz, M., Leszczynska, I.: Effect of POSS on morphology, thermal and mechanical properties of polyamide 6. Polimery 56, 11-2 (2011)
22. Kawakami, Y.: Structural control and functionalization of oligomeric silsesquioxanes. React. Funct. Polym. 67, 1137-147 (2007) CrossRef
23. Lee, A., Lichtenhan, J.D.: Viscoelastic responses of polyhedral oligosilsesquioxane reinforced epoxy systems. Macromolecules 31, 4970-974 (1998) CrossRef
24. Lin, O.H., Mohd Ishak, Z.A., Akil, H.M.: Preparation and properties of nanosilica-filled polypropylene composites with PP-methyl POSS as compatibiliser. Mater. Des. 30, 748-51 (2009) CrossRef
25. Liu, Y., Zheng, S.X., Nie, K.M.: Epoxy nanocomposites with octa(propylglycidyl ether) polyhedral oligomeric silsesquioxane. Polymer 46, 12016-2025 (2005) CrossRef
26. Mammeri, F., Bonhomme, Ch., Ribot, F., Babonneau, F., Diré, S.: New monofunctional POSS and its utilization as dewetting additive in methacrylate based free-standing films. Chem. Mater. 21, 4163-171 (2009) CrossRef
27. Qin, Y., Bi, Y., Ren, H., Zhu, F., Luo, M., Zhang, L.: Poly(methyl methacrylate)/methacryl-POSS nanocomposites with excellent thermal properties. Chin. J. Chem. 28, 2527-532 (2010) CrossRef
28. Rios, X., Moriones, P., Echeverría, J.C., Luquín, A., Laguna, M., Garrido, J.J.: Characterisation of hybrid xerogels synthesised in acid media using methyltriethoxysilane (MTEOS) and tetraethoxysilane (TEOS) as precursors. Adsorption 17, 583-93 (2011) CrossRef
29. Sarantopoulou, E., Kollia, Z., Cefalas, A.C., Siokou, A.E., Argitis, P., Bellas, V., Kobe, S.: Surface modification of polyhedral oligomeric silsesquioxane block copolymer films by 157?nm laser light. J. Appl. Phys. 105, 114-05 (2009) CrossRef
30. Schütz, M.R., Deeken, K.S., Klein, O., Adasch, V., Liebscher, Ch.H., Glatzel, U., Senker, J., Breu, J.: Sattler improvement of thermal and mechanical properties of a phenolic resin nanocomposite by in situ formation of silsesquioxanes from a molecular precursor. J. Appl. Polym. Sci. 117, 2272-277 (2010) CrossRef
31. Szwarc-Rzepka, K., Siwinska-Stefanska, K., Marciniec, B., Jesionowski, T.: Synthesis and characterisation of SiO2/POSS hybrid systems obtained using the mechanical method. Physicochem. Probl. Miner. Process. 48, 181-92 (2012a)
32. Szwarc-Rzepka, K., Ciesielczyk, F., Zawisza, M., Kaczmarek, M., Dutkiewicz, M., Marciniec, B., Maciejewski, H., Jesionowski, T.: Synthesis of hepta(isobutyl)ethyltriethoxysilyl octasilsesquioxane and its application as a modifier of both hydrated and emulsion silicas. Physicochem. Probl. Miner. Process. 48, 619-30 (2012b)
33. Thostenson, E.T., Li, Ch., Chou, T.W.: Nano-composites in context. Compos. Sci. Technol. 65, 491-16 (2005) CrossRef
34. Wheeler, P.A., Fu, B.X., Lichtenhan, J.D., Weitao, J., Mathias, L.J.: Incorporation of metallic POSS, POSS copolymers, and new functionalized POSS compounds into commercial dental resins. J. Appl. Polym. Sci. 102, 2856-862 (2006) CrossRef
35. Zhang, Ch., Laine, R.M.: Silsesquioxanes as synthetic platforms. II. Epoxy-functionalized inorganic–organic hybrid species. J. Organomet. Chem. 521, 199-01 (1996) CrossRef
36. Zhang, X., Song, Y., Huang, Y.D.: Properties of silsesquioxane coating modified carbon fibre/polyarylacetylene composites. Compos. Sci. Technol. 67, 3014-022 (2007) CrossRef
37. Zurawska, J., Krysztafkiewicz, A., Jesionowski, T.: Effect of ammonium salts on dispersive and adsorptive parameters of silicas precipitated from sodium metasilicate solution. Colloids Surf. A 223, 201-14 (2003) CrossRef - 作者单位：K. Szwarc-Rzepka (1)
B. Marciniec (2)
T. Jesionowski (1)
1. Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Poznan University of Technology, M. Sklodowskiej-Curie 2, 60965, Poznan, Poland
2. Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60780, Poznan, Poland - ISSN：1572-8757
文摘
Synthesis of octakis({3-glycidoxypropyl}dimethylsiloxy) octasilsesquioxane (G-POSS) was carried out based on a reaction involving the hydrosilylation of allyl glycidyl ether with octakis(dimethylsiloxy) octasilsesquioxane, using Karstedt’s catalyst and toluene. SiO2/POSS hybrid systems were obtained via a method of immobilization by evaporation of the solvent, using hydrated or spherical silica obtained by precipitation in an aqueous or emulsion environment. The surface of the SiO2 was modified using octakis({3-glycidoxypropyl}dimethylsiloxy) octasilsesquioxane (G-POSS). The effectiveness of the modification of the obtained hybrid materials was verified using Fourier transform infrared spectroscopy and nuclear magnetic resonance (29Si and 13C CP MAS NMR). The tests showed that the interactions between the silica support and the modifier are of the nature of chemical adsorption. In addition a mechanism was proposed for the interactions between silica and oligosilsesquioxane. To test the final effect, the hybrid systems were subjected to morphological evaluation (transmission electron microscopy). Parameters of porous structure of the products were also determined: the specific surface area, pore diameter and pore volume. Thermal stability was tested for the pure silsesquioxane cage, the initial silica supports and the resulting systems. Elemental analysis was also carried out to determine the effect of surface modification on the degree of coverage with a particular POSS compound.