A Single Fluorescent Sensor for Hg2+ and Discriminately Detection of Cr3+ and Cr(VI)

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• 作者：Jafar Afshani ; Alireza Badiei ; Mehdi Karimi ; Negar Lashgari…
• 关键词：Fluorescent sensor ; Iminocrown ether ; Mercury ; Chromium
• 刊名：Journal of Fluorescence
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：26
• 期：1
• 页码：263-270
• 全文大小：2,588 KB
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• 作者单位：Jafar Afshani (1)
  Alireza Badiei (1) (2)
  Mehdi Karimi (1)
  Negar Lashgari (1)
  Ghodsi Mohammadi Ziarani (3)
  
  1. School of Chemistry, College of Science, University of Tehran, Tehran, Iran
  2. Nanobiomedicine Center of Excellence, Nanoscience and Nanotechnology Research Center, University of Tehran, Tehran, Iran
  3. Department of Chemistry, Faculty of Science, Alzahra University, Tehran, Iran
  
• 刊物类别：Biomedical and Life Sciences
• 刊物主题：Biomedicine
  Biomedicine
  Biophysics and Biomedical Physics
  Biotechnology
  Biochemistry
  Analytical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4994

文摘

An iminocrown ether was synthesized and its fluorescence properties were studied in the presence of a variety of cations and anions in 99 % aqueous medium. The results revealed the interesting ability of the iminocrown ether in discriminately detection of Cr(III) and Cr(VI) ions in addition to detection of Hg2+ ion. Among various environmentally relevant metal ions, Cr3+ and Hg2+ enhanced and quenched the fluorescence emission, respectively and among anions only dichromate ion, Cr(VI), quenched the emission while the rest of ions insignificantly influenced the fluorescence emission. Selectivity of the iminocrown ether was also investigated and proved in the presence of excess of common competing ions. Furthermore, the fluorescence intensity of the iminocrown ether was studied as a function of concentrations of the three ions by performing a titration experiment for each one of them. The detection limits of 5.36 × 10−8, 2.06 × 10−6, and 7.49 × 10−8 mol L−1 were also calculated for Hg2+, Cr3+, and Cr(VI), respectively. Keywords Fluorescent sensor Iminocrown ether Mercury Chromium