A new access to azabicyclo[4.3.0]nonane alkaloids

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• 作者：A. V. Lozanova ; A. V. Stepanov ; V. V. Veselovsky
• 关键词：Key wordsalkaloids ; 3 ; azabicyclo[4.3.0]nonane derivatives ; silyl nitronates ; intramolecular dipolar [3+2] cycloaddition ; (L) ; (−) ; linalool ; nitro compounds
• 刊名：Russian Chemical Bulletin
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：65
• 期：3
• 页码：741-747
• 全文大小：<len>
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry/Food Science, general; Organic Chemistry; Inorganic Chemistry;
• 出版者：Springer US
• ISSN：1573-9171
• 卷排序：65

文摘

A new approach towards 3-azabicyclo[4.3.0]nonane alkaloids was implemented an intramolecular [3+2] cycloaddition of silyl nitronate generated from (L)-(−)-linalool nitro derivative, (3R,6RS)-3-acetoxy-3,7-dimethyl-6-nitro-1,7-octadiene, as a key step in the synthetic scheme.