Synthesis of group 6 metal carbonyl complexes containing oxygen- and sulfur-functionalized 1,2,4-triazoles

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• 作者：Yang Yu ; Xiao-Yan Zhang ; Juan Hong ; Hai-Bin Song and Liang-Fu Tang
• 刊名：Transition Metal Chemistry
• 出版年：2009
• 出版时间：October, 2009
• 年：2009
• 卷：34
• 期：7
• 页码：791-795
• 全文大小：217.4 KB

文摘

Reaction of RCOCH₂Tz and PhCOCH(CH₂SPh)Tz with M(CO)₆ or M(CO)₅THF results in RCOCH₂TzM(CO)₅ and PhCOCH(CH₂SPh)TzM(CO)₅ (R = phenyl or ferrocenyl, Tz = 1,2,4-triazol-1-yl and M = Mo or W). X-ray crystal structure analyses show that the triazolyl group acts as a monodentate ligand through the exodentate nitrogen atom in these complexes. The electrochemical behavior of these complexes has been investigated by cyclic voltammetry.