Crystallization and phase homogeneity of [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine-4,6-dioxide-,4-dinitro2,4-diazapentane molecular complex

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• 作者：P. I. Kalmykov ; V. V. Zakharov ; N. V. Chukanov…
• 关键词：[1 ; 2 ; 5]oxadiazolo[3 ; 4 ; e][1 ; 2 ; 3 ; 4]tetrazine ; 4 ; 6 ; dioxide (furazanotetrazinedioxide) ; 2 ; 4 ; dinitro2 ; 4 ; diazapentane ; molecular complex ; eutectics ; crystallization ; turbidimetry ; DSC ; IR spectroscopy ; thermal transformations
• 刊名：Russian Journal of Physical Chemistry B, Focus on Physics
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：9
• 期：5
• 页码：714-720
• 全文大小：570 KB
• 参考文献：1.A. S. Zharkov, P. I. Kalmykov, Yu. N. Burtsev, et al., Izv. Akad. Nauk, Ser. Khim. 64, 1785 (2014).
  2.P. I. Kalmykov, A. A. Sidel’nikov, A. I. Ancharov, et al., in Proceedings of the 4th All-Russia Conference on Energetic Condensed Systems (Inst. Prikl. Khim. Fiz. RAN, Chernogolovka, 2008), p. 26.
  3.P. I. Kalmykov, V. E. Zarko, A. A. Sidel’nikov, I. V. Koptyug, A. I. Ancharov, K. A. Sidorov, Russ. J. Appl. Chem. 84, 248 (2011).CrossRef
  4.P. I. Kalmykov, V. E. Zarko, V. N. Simonenko, et al., in Proceedings of the 5th All-Russia Conference on Energetic Condensed Systems (Inst. Prikl. Khim. Fiz. RAN, Chernogolovka, 2010), p. 134.
  5.L. N. Matusevich, Crystallization from Solutions in the Chemical Industry (Khimiya, Moscow, 1968) [in Russian].
  6.P. I. Kalmykov, Yu. N. Burtsev, N. P. Kuznetsova, et al., in Proceedings of the 6th All-Russia Conference on Power Condensed Systems (Inst. Prikl. Khim. Fiz. RAN, Chernogolovka, 2012), p. 54.
  7.O. V. Travin and N. T. Travina, Materials Science (Metallurgiya, Moscow, 1989) [in Russian].
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• 作者单位：P. I. Kalmykov (1)
  V. V. Zakharov (2)
  N. V. Chukanov (2)
  B. L. Korsounskii (2) (3)
  K. A. Sidorov (1)
  E. V. Artemova (1)
  
  1. OAO Federal Research and Production Center “Altai- Biisk, Russia
  2. Institute of Problem of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Mosscow oblast, Russia
  3. National Research Nuclear University MePhI, Moscow, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1990-7923

文摘

The thermally reversible processes of melting and crystallization of the [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine-4,6-dioxide-,4-dinitro-2,4-diazapentane equimolar molecular complex produced in various technological modes of its isolation from the melt are studied and optimized by using turbidimetry, optical microscopy, and differential scanning calorimetry. The kinetic factors of the stepwise crystallization of the complex related to both the formation of nucleation sites and growth of the crystals are identified. A colorimetric method for controlling the phase purity and evaluating the content of impurities in the molecular complex after their preliminary identification by infrared spectroscopy is developed. Keywords [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine-4,6-dioxide (furazanotetrazinedioxide) 2,4-dinitro2,4-diazapentane molecular complex eutectics crystallization turbidimetry DSC IR spectroscopy thermal transformations