Structure and photoluminescent property of a three-dimensional pillared-layer La(III)-Cu(I) heterometallic coordination polymer

详细信息    查看全文

• 作者：X. Li (1)
  H. Zhao (1)
  Q. Zeng (1)
  
• 关键词：heterometallic coordination polymer ; crystal structure ; pillared ; layer ; photoluminescent property
• 刊名：Journal of Structural Chemistry
• 出版年：2014
• 出版时间：January 2014
• 年：2014
• 卷：55
• 期：1
• 页码：96-100
• 全文大小：305 KB
• 参考文献：1. M. Shibasaki and N. Yoshikawa, / Chem. Rev., 102, 2187 (2002). CrossRef
  2. E. Chelebaeva, J. Larionova, Y. Guari, et al., / Inorg. Chem., 47, 775 (2008). CrossRef
  3. M. Andruh, J. P. Costes, C. Diaz, et al., / Inorg. Chem., 48, 3342 (2009). CrossRef
  4. O. Guillou, C. Daiguebonne, M. Camara, et al., / Inorg. Chem., 45, 8468 (2006). CrossRef
  5. J. Jankolovits, J. W. Kampf, S. Maldonado, et al., / Chem. Eur. J., 16, 6786 (2010). CrossRef
  6. C. E. Plecnik, S. Liu, and S. G. Shore, / Acc. Chem. Res., 36, 499 (2003). CrossRef
  7. J. W. Cheng, J. Zhang, S. T. Zheng, et al., / Angew. Chem. Int. Ed., 45, 73 (2006). CrossRef
  8. Y. P. Cai, X. X. Zhou, Z. Y. Zhou, et al., / Inorg. Chem., 48, 6341 (2009). CrossRef
  9. Q. B. Bo, G. X. Sun, and D. L. Geng, / Inorg. Chem., 49, 561 (2010). CrossRef
  10. M. Chen, M. S. Chen, T. Okamura, et al., / CrystEngComm., 13, 3801 (2011). CrossRef
  11. Z. Y. Li, J. W. Dai, N. Wang, et al., / Cryst. Growth Des., 10, 2746 (2010). CrossRef
  12. Y. G. Sun, Y. L. Wu, G. Xiong, et al., / Dalton Trans., 39, 11383 (2010). CrossRef
  13. L. Q. Fan, J. H. Wu, and Y. F. Huang, / J. Solid State Chem., 184, 2472 (2011). CrossRef
  14. J. W. Cheng, S. T. Zheng, and G. Y. Yang, / Inorg. Chem., 47, 4930 (2008). CrossRef
  15. X. F. Li, Y. B. Huang, and R. Cao, / Cryst. Growth Des., 12, 3549 (2012). CrossRef
  16. M. B. Zhang, H. M. Chen, and R. X. Hu, / Z. Anorg. Allg. Chem., 636, 2665 (2010). CrossRef
  17. J. Y. Lee, S. Y. Lee, W. Sim, et al., / J. Am. Chem. Soc., 130, 6902 (2008). CrossRef
  18. X. J. Gu and D. F. Xue, / Cryst. Growth Des., 7, 1726 (2007). CrossRef
  19. X. J. Gu and D. F. Xue, / Inorg. Chem., 46, 5349 (2007). CrossRef
  20. J. J. M. Amoore, L. R. Hanton, and M. D. Spicer, / Dalton Trans., 1056 (2003).
  21. R. G. Pearson, / J. Am. Chem. Soc., 85, 3533 (1963). CrossRef
  22. G. M. Sheldrick, / SHELXS-97, Program for Solution of Crystal Structures, Univ. G?ttingen, Germany (1997).
  
• 作者单位：X. Li (1)
  H. Zhao (1)
  Q. Zeng (1)
  
  1. Department of Chemistry, Zunyi Normal College, Zunyi, P. R. China
  
• ISSN：1573-8779

文摘

A three-dimensional (3D) pillared-layer La(III)-Cu(I) heterometallic coordination polymer (HCP) formulated as [La2Cu4I3(Hina)7(H2O)] n (1) (Hina = isonicotinic acid), is synthesized by a hydrothermal reaction of La2O3, CuI, and ina. The crystal structure is determined by single crystal X-ray diffraction. HCP 1 crystallizes in the monoclinic space group P21/c with unit cell parameters: a = 17.0147(3) ?, b = 18.4431(3) ?, c = 16.7487(3) ?, β = 102.469(2)°, V = 5131.84(15) ?3, Z = 4. It features a 3D pillared-layer heterometallic organic framework, where Ln-ina layers are pillared by discrete [Cu8I6(ina)12] units along the direction of the a axis. In addition, the solid-state photoluminescent property is investigated.