Enhancing heterogeneous catalytic activity of iron (II) phthalocyanine by ethanol and its application in 2,4-dichlorophenol detection
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- 作者：Yilin Tong (1) (2)
Dapeng Li (3)
Jun Huang (1) (2)
Kun Li (1) (2)
Liyun Ding (1) (2)
Tianxia Wang (1) (2)
Jingjing Gong (1) (2) - 关键词：iron (II) phthalocyanine ; 2 ; 4 ; dichlorophenol ; catalysis ; chromogenic reaction
- 刊名：Journal of Wuhan University of Technology--Materials Science Edition
- 出版年：2014
- 出版时间：June 2014
- 年：2014
- 卷：29
- 期：3
- 页码：567-571
- 全文大小：
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Dapeng Li (3)
Jun Huang (1) (2)
Kun Li (1) (2)
Liyun Ding (1) (2)
Tianxia Wang (1) (2)
Jingjing Gong (1) (2)
1. National Engineering Laboratory for Fiber Optic Sensing Technology, Wuhan University of Technology, Wuhan, 430070, China
2. Key Laboratory of Fiber Optic Sensing Technology and Information Processing (Wuhan University of Technology), Ministry of Education, Wuhan, 430070, China
3. Key Laboratory for Micro-Nano Energy Storage and Conversion Materials of Henan Province, School of Chemistry and Chemical Engineering, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, 461000, China - ISSN：1993-0437
文摘
A chemical system for facile and accurate detection of 2,4-dichlorophenol (DCP) via iron (II) phthalocyanine (Fe(II)Pc) catalyzed chromogenic reaction is reported for the first time. In this system, DCP could be oxidized by dioxygen with the catalysis of Fe(II)Pc and then coupled with 4-aminoantipyrine (4-AAP) to generate pink antipyrilquinoneimine dye. Control experiments showed that the addition of ethanol could obviously enhance the catalytic activity of heterogeneous Fe(II)Pc catalysts because of the partial dissolution of Fe(II)Pc nanocubes, which was confirmed by the SEM analysis. On the basis of the detection results of DCP in the range from 2×10 to 9×10 mol/L, we obtained a regression equation (A = 0.187 5 + 0.01 209C (R 2=0.995 6)) with the detection limit (3σ) of 3.26×10 mol/L, which could be successfully used in detecting the real samples.