Synthesis and Surface-Active Behavior of New Fluorinated Hyperbranched Polymer

详细信息    查看全文

• 作者：Yue Zhang (1)
  Yan Wang (1)
  Huimin Zhang (1)
  Xi Wang (1)
  Yongxiang Zhao (1)
  Jun Liu (2)
  Feng Wang (2)
  
• 关键词：Surface tension ; Interfacial tension ; Trifluoroethyl methacrylate ; Hyperbranched
• 刊名：Journal of Surfactants and Detergents
• 出版年：2014
• 出版时间：September 2014
• 年：2014
• 卷：17
• 期：5
• 页码：967-975
• 全文大小：489 KB
• 参考文献：1. Yan D, Gao C, Frey H (2011) Hyperbranched polymers: synthesis, properties, and applications. Wiley, New York CrossRef
  2. Yates CR, Hayes W (2004) Synthesis and applications of hyperbranched polymers. Eur Polym J 40:1257-281 CrossRef
  3. Voit B (2005) Hyperbranched polymers—all problems solved after 15?years of research? J Polym Sci Part A Polym Chem 43:2679-699 CrossRef
  4. Chang CJ, Hsieh SR, Wang C-C, Hung TW, Hsieh CC (2012) Surface-modified long-chain branching hyperbranched polymer for postsurgical anti-adhesion applications. Polym Int 62:974-82 CrossRef
  5. Dong Z, Ye Z (2012) Hyperbranched polyethylenes by chain walking polymerization: synthesis, properties, functionalization, and applications. Polym Chem 3:286-01 CrossRef
  6. Jin H, Huang W, Zhu X, Zhou Y, Yan D (2012) Biocompatible or biodegradable hyperbranched polymers: from self-assembly to cytomimetic applications. Chem Soc Rev 41:5986-997 CrossRef
  7. Olofsson K, Andrén OCJ, Malkoch M (2014) Recent advances on crosslinked dendritic networks. J Appl Polym Sci 131. doi:10.1002/app.39876
  8. Peleshanko S, Tsukruk VV (2008) The architectures and surface behavior of highly branched molecules. Prog Polym Sci 33:523-80 CrossRef
  9. Reuter S, Hofmann AM, Busse K, Frey H, Kressler J (2010) Langmuir and Langmuir–Blodgett films of multifunctional, amphiphilic polyethers with cholesterol moieties. Langmuir 27:1978-989 CrossRef
  10. Joseph N, Ahmadiannamini P, Hoogenboom R, Vankelecom IFJ (2014) Layer-by-layer preparation of polyelectrolyte multilayer membranes for separation. Polym Chem 5:1817-831 CrossRef
  11. Zhai X, Peleshanko S, Klimenko NS, Genson KL, Vaknin D, Vortman MY, Shevchenko VV, Tsukruk VV (2003) Amphiphilic dendritic molecules: hyperbranched polyesters with alkyl-terminated branches. Macromolecules 36:3101-110 CrossRef
  12. Peleshanko S, Gunawidjaja R, Petrash S, Tsukruk VV (2006) Synthesis and interfacial behavior of amphiphilic hyperbranched polymers: poly(ethylene oxide)—polystyrene hyperbranches. Macromolecules 39:4756-766 CrossRef
  13. Samuel AZ, Ramakrishnan S (2013) Self-adapting peripherally heterofunctionalized hyperbranched polymers: formation of Janus and tripodal structures. Langmuir 29:1245-257 CrossRef
  14. Samuel AZ, Ramakrishnan S (2012) Janus Hybramers: self-adapting amphiphilic hyperbranched polymers. Macromolecules 45:2348-358 CrossRef
  15. Zhang Y, Yan Y, Wang Y, Li Y, Wang X, Zhang H, Liu J, Wang F (2013) The synthesis and solution properties of hyperbranched polyglycerols modified with hexafluorobutyl acrylate. Colloids Surf A 436:563-69 CrossRef
  16. París R, de la Fuente JL (2005) Solvent effect on the atom transfer radical polymerization of allyl methacrylate. J Polym Sci Part A Polym Chem 43:6247-261 CrossRef
  17. Nanda AK, Matyjaszewski K (2003) Effect of [bpy]/[Cu(I)] ratio, solvent, counterion, and alkyl bromides on the activation rate constants in atom transfer radical polymerization. Macromolecules 36:599-04 CrossRef
  18. Bergenudd H, Coullerez G, Jonsson M, Malmstr?m E (2009) Solvent effects on ATRP of oligo(ethylene glycol) methacrylate. Exploring the limits of control. Macromolecules 42:3302-308 CrossRef
  19. Horn M, Matyjaszewski K (2013) Solvent effects on the activation rate constant in atom transfer radical polymerization. Macromolecules 46:3350-357 CrossRef
  20. Matyjaszewski K (2003) The synthesis of functional star copolymers as an illustration of the importance of controlling polymer structures in the design of new materials. Polym Int 52:1559-565 CrossRef
  21. Matyjaszewski K, Xia J (2001) Atom transfer radical polymerization. Chem Rev 101:2921-990 CrossRef
  22. Brochon C, Sary N, Mezzenga R, Ngov C, Richard F, May M, Hadziioannou G (2008) Synthesis of poly(paraphenylene vinylene)—polystyrene-based rod-coil block copolymer by atom transfer radical polymerization: toward a self-organized lamellar semiconducting material. J Appl Polym Sci 110:3664-670 CrossRef
  23. Alfredo NV, Jalapa NE, Morales SL, Ryabov AD, Le Lagadec R, Alexandrova L (2012) Light-driven living/controlled radical polymerization of hydrophobic monomers catalyzed by ruthenium(II) metallacycles. Macromolecules 45:8135-146 CrossRef
  24. Liu C, Wang G, Zhang Y, Huang J (2008) Preparation of star polymers of hyperbranched polyglycerol core with multiarms of PS-b-PtBA and PS-b-PAA. J Appl Polym Sci 108:777-84 CrossRef
  25. Maier S, Sunder A, Frey H, Mülhaupt R (2000) Synthesis of poly(glycerol)-block-poly(methyl acrylate) multi-arm star polymers. Macromol Rapid Commun 21:226-30 CrossRef
  26. Xia J, Gaynor SG, Matyjaszewski K (1998) Controlled/“living-radical polymerization. Atom transfer radical polymerization of acrylates at ambient temperature. Macromolecules 31:5958-959 CrossRef
  27. Alexandridis P, Athanassiou V, Fukuda S, Hatton TA (1994) Surface activity of poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) copolymers. Langmuir 10:2604-612 CrossRef
  28. Kausch CM, Kim Y, Russell VM, Medsker RE, Thomas RR (2003) Surface tension and adsorption properties of a series of bolaamphiphilic poly(fluorooxetane)s. Langmuir 19:7182-187 CrossRef
  29. Li G-L, Gao Y-A, Li X-W, Liu J, Zheng L-Q, Xing H, Xiao J-X (2010) Aggregation behavior of / N-alkyl perfluorooctanesulfonamides in dimethyl sulfoxide solution. J Colloid Interface Sci 342:372-81 CrossRef
  30. Shi L, Li N, Zheng L (2011) Aggregation behavior of long-chain / N-aryl imidazolium bromide in a room temperature ionic liquid. J Phys Chem C 115:18295-8301 CrossRef
  31. Srinivasa Rao K, Singh T, Trivedi TJ, Kumar A (2011) Aggregation behavior of amino acid ionic liquid surfactants in aqueous media. J Phys Chem B 115:13847-3853
  32. Rosen MJ, Kunjappu JT (2012) Surfactants and interfacial phenomena. Wiley, New York CrossRef
  
• 作者单位：Yue Zhang (1)
  Yan Wang (1)
  Huimin Zhang (1)
  Xi Wang (1)
  Yongxiang Zhao (1)
  Jun Liu (2)
  Feng Wang (2)
  
  1. College of Chemistry and Chemical Engineering, Engineering Research Center of Ministry of Education for Fine Chemicals, Shanxi University, Taiyuan, 030006, People’s Republic of China
  2. National High-tech Industrial Development Zones of Taiyuan, Taiyuan, 030006, People’s Republic of China
  
• ISSN：1558-9293

文摘

In this article, a series of novel hyperbranched fluorinated polymer with polyglycerol (PG) as the hydrophilic core and poly(2,2,2-trifluoroethyl methacrylate) (PTFEMA) as solvophobic arms were synthesized. When the atom transfer radical polymerization was carried out using N,N-dimethylformamide (DMF) as the solvent, [M]/[I] ratio of 200, and [CuBr]/[N Br] ratio of 0.1 at 30?°C, controlled polymerization was achieved. The surface active properties of the polymer at the dimethyl sulfoxide (DMSO)/air and chloroform/water interface were studied by pendant drop measurements. The results showed that the copolymers could reduce surface tension (interfacial tension) in a manner analogous to the conventional surfactant in aqueous solutions. Thermodynamic analysis suggested that the solvophobic PTFEMA chains play an important role in determining the driving force of the aggregate formation in DMSO.