Phosphoric acid-based preparing of chitin nanofibers and nanospheres
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- 作者：Tao Wu ; Guoqing Wang ; Chengxin Gao ; Zhigang Chen ; Li Feng ; Peng Wang…
- 关键词：Chitin nanofibers ; Nanospheres ; Phosphoric acid ; Dissolution ; Regeneration ; Temperature
- 刊名：Cellulose
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：23
- 期：1
- 页码：477-491
- 全文大小：2,945 KB
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Guoqing Wang (1)
Chengxin Gao (1)
Zhigang Chen (1)
Li Feng (2)
Peng Wang (2)
Xiaoxiong Zeng (2)
Zhongwei Wu (3)
1. Glycomics and Glycan Bioengineering Research Center (GGBRC), College of Food Science and Technology, Nanjing Agricultural University, Weigang 1, Nanjing, 210095, People’s Republic of China
2. College of Food Science and Technology, Nanjing Agricultural University, Weigang 1, Nanjing, 210095, People’s Republic of China
3. College of Life Science and Technology, Henan Institute of Science and Technology, Xinxiang, 453003, People’s Republic of China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Bioorganic Chemistry
Physical Chemistry
Organic Chemistry
Polymer Sciences - 出版者：Springer Netherlands
- ISSN：1572-882X
文摘
Chitin nanofibers and nanospheres were prepared by dissolution of the polymer in phosphoric acid and regeneration in water. Up to 4 % chitin was readily soluble in concentrated phosphoric acid. By varying the dissolution temperatures and times, chitin nanofibers with widths around 20 nm or chitin nanospheres with sizes around 200–500 nm were obtained with yields more than 80 %. Chemical composition analysis showed that the chemical structures of native chitin were essentially remained after the dissolution and regeneration process, and the degree of substitution of phosphorous on chitin chain was less than 1.00 %. Crystalline structure analysis revealed the crystalline structure of native chitin was not altered, but the crystallinity was decreased after regeneration. Our findings offers a facile and green process for most common labs to prepare chitin nanomaterials with tuned morphology in high yields, which may find great applications in the biomedical, pharmaceutical and food industries. Keywords Chitin nanofibers Nanospheres Phosphoric acid Dissolution Regeneration Temperature