Synthesis and crystallization behavior of novel poly(butylene succinate) copolyesters containing phosphorus pendent groups

详细信息    查看全文

• 作者：Cheng Zhou ; Zhiyong Wei ; Yang Yu ; Yang Li
• 关键词：Poly(butylene succinate) ; Crystallization ; Melting behavior ; Phosphorus containing
• 刊名：Journal of Thermal Analysis and Calorimetry
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：120
• 期：3
• 页码：1799-1810
• 全文大小：1,837 KB
• 参考文献：1.Han HY, Wang XD, Wu DZ. Mechanical properties, morphology and crystallization kinetic studies of bio-based thermoplastic composites of poly(butylene succinate) with recycled carbon fiber. J Chem Technol Biotechnol. 2013;88:1200-1.View Article
  2.Miyata T, Masuko T. Crystallization behaviour of poly(tetramethylene succinate). Polymer. 1998;39:1399-04.View Article
  3.Wei ZY, Chen GY, Shi YM, Song P, Zhan MQ, Zhang WX. Isothermal crystallization and mechanical properties of poly(butylene succinate)/layered double hydroxide nanocomposites. J Polym Res. 2012;19:9930-0.View Article
  4.Soccio M, Lotti N, Munari A. Influence of block length on crystallization kinetics and melting behavior of poly(butylene/thiodiethylene succinate)block copolymers. J Therm Anal Calorim. 2013;114:677-8.View Article
  5.Chen L, Wang YZ. A review on flame retardant technology in China. Part I: development of flame retardants. Polym Adv Technol. 2010;21:1-6.View Article
  6.Levchik SV, Weil ED. Flame retardancy of thermoplastic polyesters—a review of the recent literature. Polym Int. 2005;54:11-5.View Article
  7.Zhang C, Huang JY, Liu SM, Zhao JQ. The synthesis and properties of a reactive flame-retardant unsaturated polyester resin from a phosphorus-containing diacid. Polym Adv Technol. 2011;22:1768-7.View Article
  8.Chang SJ, Chang FC. Synthesis and characterization of copolyesters containing the phosphorus linking pendent groups. J Appl Polym Sci. 1999;72:109.View Article
  9.Lu SY, Hamerton I. Recent developments in the chemistry of halogen-free flame retardant polymers. Prog Polym Sci. 2002;27:1661-12.View Article
  10.Brehme S, Schartel B, Goebbels J, Fischer O, Pospiech D, Bykov Y, D?ring M. Phosphorus polyester versus aluminium phosphinate in poly(butylene terephthalate) (PBT): flame retardancy performance and mechanisms. Polym Degrad Stab. 2011;96:875-4.View Article
  11.Chang SJ, Sheen YC, Chang RS, Chang FC. The thermal degradation of phosphorus-containing copolymers. Polym Degrad Stab. 1996;54:365-1.View Article
  12.Wang DY, Song YP, Lin L, Wang XL, Wang YZ. A novel phosphorus-containing poly(lactic acid) toward its flame retardation. Polymer. 2011;52:233-.View Article
  13.Sablong R, Duchateau R, Koning CE, Pospiech D, Korwitz A, Komber H, Starke S, H?u?ler L, Jehnichen D, Landwehr MA. Incorporation of a flame retardancy enhancing phosphorus-containing diol into poly(butylene terephthalate) via solid state polycondensation: a comparative study. Polym Degrad Stab. 2011;96:334-1.View Article
  14.Li J, Zhu HF, Li J, Fan XY, Tian XY. Thermal degradation behaviors of phosphorus-silicon synergistic flame-retardant copolyester. J Appl Polym Sci. 2011;122:1993-003.View Article
  15.Chang SJ, Chang FC. Sequential distribution of copolyesters containing the phosphorus linking pendant groups characterized by 1H-n.m.r. Polymer. 1998;39:3233-0.View Article
  16.Chang SJ, Chang FC. Characterizations for blends of phosphorus-containing copolyester with poly(ethylene terephthalate). Polym Eng Sci. 1998;38:1471-1.View Article
  17.Wang DY, Wei LL, Ge XG, Yang KK, Wang XL, Wang YZ. Nonisothermal crystallization behaviors of flame-retardant copolyester/montmorillonite nanocomposites. J Macromol Sci Phys. 2009;48:927-0.View Article
  18.Chen HB, Zhang Y, Chen L, Shao ZB, Liu Y, Wang YZ. Novel inherently flame-retardant poly(trimethylene terephthalate) copolymer with the phosphorus-containing linking pendent group. Ind Eng Chem Res. 2010;49:7052-.View Article
  19.Chen HB, Zeng JB, Dong X, Chen L, Wang YZ. Block phosphorus-containing poly(trimethylene terephthalate) copolymer via solid-state polymerization: retarded crystallization and melting behaviour. Cryst Eng Comm. 2013;15:2688-8.View Article
  20.Jin TX, Zhou M, Hu SD, Chen F, Fu Q. Effect of molecular weight on the properties of poly(butylene succinate). Chin J Polym Sci. 2014;32:953-0.View Article
  21.Tan LC, Chen YW, Zhou WH, Ye SW. crystallization behavior and mechanical strength of poly(butylene succinate-co-ethylene glycol) based nanocomposites using functionalized multiwalled carbon nanotubes. Polym Eng Sci. 2012;52:2506-7.View Article
  22.Tan LC, Chen YW, Zhou WH, Nie HR, Li F, He XH. Novel poly(butylene succinate-co-lactic acid) copolymers: synthesis, crystallization, and enzymatic degradation. Polym Degrad Stab. 2010;95:1920-.View Article
  23.Park JW, Kim DK, Im SS. Crystallization behaviour of poly(butylene succinate) copolymers. Polym Int. 2002;51:239-4.View Article
  24.Papageorgiou GZ, Bikiaris DN. Crystallization and melting behavior of three biodegradable poly(alkylene succinates). A comparative study. Polymer. 2005;46:12081-2.View Article
  25.Yang Y, Qiu ZB. Crystallization kinetics and morphology of biodegradable poly(butylene succinate-co-ethylene succinate) copolyesters: effects of comonomer composition and crystallization temperature. Cryst Eng Comm. 2011;13:2408-7.View Article
  26
• 作者单位：Cheng Zhou (1)
  Zhiyong Wei (1)
  Yang Yu (1)
  Yang Li (1)
  
  1. State Key Laboratory of Fine Chemicals, Department of Polymer Science and Materials, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Sciences
  Polymer Sciences
  Physical Chemistry
  Inorganic Chemistry
  Measurement Science and Instrumentation
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1572-8943

文摘

Novel biodegradable poly(butylene succinate) (PBS) copolyesters containing phosphors flame-retardant groups were synthesized by melt-polycondensation from succinic acid and 9,10-dihydro-10-[2,3-di(hydroxycarbonyl)propyl]-10-phosphaphenanthrene-10-oxide (DDP) with 1,4-butanediol. In order to analyze the effects of the third monomer (DDP) on the relative properties of PBS, the composition, crystal structure, crystallization behavior, multiple melting behavior, and spherulitic morphology of the copolyesters were investigated by 1H-NMR, WAXD, DSC, and POM, respectively. WAXD data revealed that the crystal structure of PBS was not affected by DDP. The overall crystallization kinetic showed that the crystallization of PBS was retarded with the introduction of DDP, especially when the DDP content exceeds 7.5?mol%, which may result from the stereo-hindrance of DDP unit. Furthermore, crystallization temperature (T _c), crystallization enthalpy (ΔH _c), melting temperature (T _m), and crystallinity (X _c) of PBS copolyesters also decreased apparently with the increase in DDP contents. Also, the equilibrium melting temperature (T _m o ) obtained from Hoffman-Weeks analysis decreased, indicating that the regularity of PBS chain segments was reduced probably due to the diluent effect of the specific chain structure of DDP. All spherulites showed the ring-banded extinction patterns, which implied that phosphorus-containing (DDP) segment did not change the growth mechanism of PBS crystals.