• journal_title：European Journal of Mineralogy
• Contributor：Clément Courtieu ; François-Xavier D’abzac ; Jérôme Chmeleff ; Damien Guillaume ; Anne-Magali Seydoux-Guillaume
• Publisher：E. Schweizerbart'sche Verlagsbuchhandlung Science Publishers
• Date：2011-
• Format：text/html
• Language：en
• Identifier：10.1127/0935-1221/2011/0023-2113
• journal_abbrev：Eur J Mineral
• issn：0935-1221
• volume：23
• issue：3
• firstpage：391
• section：EMPG XII, Toulouse: Experimental Mineralogy, Petrology and Geochemistry Symposium

A commercial femtosecond laser system operating at its fundamental wavelength (λ = 800 nm, near Infra-Red) was used to ablate both synthetic and natural quartz on polished and unpolished surfaces. Ablation rates and maximum depths were determined using two distinct optical setups: a 25 mm focal length Cassegrain reflecting objective, and a 50 mm focal length convergent coated lens. All samples were ablated with the same laser beam at E₀ = 1 mJ, τ = 60 fs, f = 5 Hz and N = 10–8000 shots. The depth of ablation craters obtained with the lens shows a linear increase with shot number N up to N = 2000 shots. Then the depth increases much less with N and reaches a plateau above N = 3000 shots. Maximum depth was close to 1300 μm for N = 3000 shots. Using the reflecting objective, ablation rate starts from 0.42 μm/shot and decreases rapidly to 0.02 μm/shot at a maximum depth of 350 μm for N =1500 shots. Ablation thresholds (F_th) were calculated for 1 and 10 consecutive shots with energy increasing from E₀ = 0.1–2 mJ/pulse. Threshold values varies from F_th=0.1 J.cm⁻² (unpolished, 10 shots) to F_th = 2.9 J.cm⁻² (polished, single shot). The energy penetration of IR-femtosecond laser pulses in quartz has been calculated at l = 271 nm. The low absorption of IR wavelengths in quartz affects the ablation efficiency in the first shots. The associated non-linear effects are visible on a crater FIB foil observed with TEM as progressive high-pressure photomechanical damage developing under the ablation pit. The present study emphasizes the potential of IR-femtosecond laser for ablation of highly transparent material, and provides reliable data for LA-ICP-MS applications in earth sciences.