An investigation was carried out concerning the origin of carbon in the following pre-Cambrian materials from Finland: graphite, carbon-bearing schists, carbonaceous accumulations in phyllites including the suggested fossil Corycium enigmaticum Sederholm; shungite from Karelo-Finnish S.S.R. Geological and petrological descriptions of the materials investigated are given. CuO, V<sub>2sub>O<sub>5sub>, and MoO<sub>3sub> contents of the samples and the isotope ratios C<sup>12sup>/C<sup>13sup> in carbon extracted from same are presented. Geological evidence and trace-element determinations make probable the division of carbon in these samples into organic and inorganic groups; the mass spectrometric C<sup>12sup>/C<sup>13sup> determinations furnish definite proof of this and also final proof of the organic nature of the Corycium which thus is a real fossil of the Late Archean time, the oldest ever recorded with definite certainty.